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Wednesday, August 28, 2013

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

Graphical abstract: Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

Chem. Sci., 2013,4, 3912-3916

Pd(ii)-catalyzed alkylation of unactivated C(sp3)–H bonds: efficient synthesis of optically active unnatural α-amino acids

Graphical abstract: Pd(ii)-catalyzed alkylation of unactivated C(sp3)–H bonds: efficient synthesis of optically active unnatural α-amino acids

Chem. Sci., 2013,4, 3906-3911

Cu(i)-catalyzed intramolecular oxidative C–H amination of 2-aminoacetophenones: a convenient route toward isatins

Graphical abstract: Cu(i)-catalyzed intramolecular oxidative C–H amination of 2-aminoacetophenones: a convenient route toward isatins
Chem. Commun., 2013,49, 8540-8542

A convenient synthesis of quinolizinium salts through Rh(iii) or Ru(ii)-catalyzed C–H bond activation of 2-alkenylpyridines

Graphical abstract: A convenient synthesis of quinolizinium salts through Rh(iii) or Ru(ii)-catalyzed C–H bond activation of 2-alkenylpyridines
Chem. Commun., 2013,49, 8528-8530

Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl C[BOND]H Activation

DOI: 10.1002/chem.201300829

Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C[BOND]H Bond Activation

DOI: 10.1002/chem.201301987

Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes

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New Strategies for Transition-Metal-Catalyzed C-P Bond Formation

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Sunday, August 25, 2013

Aerobic C–H Acetoxylation of 8-Methylquinoline in PdII–Pyridinecarboxylic Acid Systems: Some Structure–Reactivity Relationships

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Rh(III)-Catalyzed Tandem C–H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles

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Cu-Catalyzed Cross-Dehydrogenative Coupling Reactions of (Benzo)thiazoles with Cyclic Ethers

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Carboxylate Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes

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Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

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A Versatile Approach to Ullmann C–N Couplings at Room Temperature: New Families of Nucleophiles and Electrophiles for Photoinduced, Copper-Catalyzed Processes

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Bioconjugation by Native Chemical Tagging of C–H Bonds

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Pt-Catalyzed C–C Activation Induced by C–H Activation

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Palladium-Catalyzed Allylic C–H Fluorination

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Tuesday, August 20, 2013

Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl C[BOND]H Activation

Palladium/Copper-Catalyzed Oxidative C[BOND]H Alkenylation/N-Dealkylative Carbonylation of Tertiary Anilines

Palladium/Copper-Catalyzed Oxidative C[BOND]H Alkenylation/N-Dealkylative Carbonylation of Tertiary Anilines

Regioselective Hydroarylations and Parallel Kinetic Resolution of Vince Lactam

Palladium-Catalyzed Hydrobenzylation of ortho-Tolyl Alkynyl Ethers by Benzylic C[BOND]H Activation: Remarkable Alkynoxy-Directing Effect

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Allenes by the [3+2] Annulation of Aryl Ketimines

Wednesday, August 14, 2013

l-Proline–TBAB-catalyzed phosgene free synthesis of methyl carbamates from amines and dimethyl carbonate

Graphical abstract: l-Proline–TBAB-catalyzed phosgene free synthesis of methyl carbamates from amines and dimethyl carbonate

Atropodiastereoselective C[BOND]H Olefination of Biphenyl p-Tolyl Sulfoxides with Acrylates

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Metal-Free Oxidative Coupling: Xanthone Formation via Direct Annulation of 2-Aryloxybenzaldehyde using Tetrabutylammonium Bromide as a Promoter in Aqueous Medium

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Silver-Catalyzed Decarboxylative Acylarylation of Acrylamides with α-Oxocarboxylic Acids in Aqueous Media

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Switchable Synthesis of 3-Cyanoindoles and 3-Amidylindoles via a Palladium-Catalyzed Reaction of N,N-Dimethyl-2-alkynylaniline with Isocyanide

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8-Aminoquinoline: A Powerful Directing Group in Metal-Catalyzed Direct Functionalization of C[BOND]H Bonds

DOI: 10.1002/anie.201303556

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