Palladium-Catalyzed Selective β-Arylation of Aliphatic Amides Using a Removable N,O-Bidentate Auxiliary

The Role of Fluorine Substituents in the Regioselectivity of Intramolecular C–H Bond Functionalization of Benzylamines at Palladium(II)

Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C–O Bond Cleavage

Palladium-Catalyzed Oxidative Arylation of Tertiary Benzamides: Para-Selectivity of Monosubstituted Arenes

Palladium-Catalyzed Oxidative Direct C3- and C7-Alkenylations of Indazoles: Application to the Synthesis of Gamendazole

Ortho-C–H Benzylation of Aryl Imines with Benzyl Phosphates under Cobalt–Pyphos Catalysis

Modern Organic Synthesis with α-Diazocarbonyl Compounds

Practical Pd(II)-Catalyzed C–H Alkylation with Epoxides: One-Step Syntheses of 3,4-Dihydroisocoumarins

N-Difluoromethylthiophthalimide: A Shelf-Stable, Electrophilic Reagent for Difluoromethylthiolation

Ir(III)-Catalyzed Oxidative Coupling of NH Isoquinolones with Benzoquinone

DOI: 10.1021/acs.orglett.5b01974

Palladium(II)-Catalyzed Direct C–H Alkenylation of Thienothiophene and Related Fused Heteroarenes

DOI: 10.1021/acs.orglett.5b02246

Cu(II)-Mediated C(sp2)–H Hydroxylation

Cationic Rhodium(III)-Catalyzed Direct C-2 Carboxamidation of Indoles with Isocyanates via C[BOND]H Bond Functionalization

A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate

doi:10.1038/nchem.2322

Dehydrogenative Carbon–Carbon Bond Formation Using Alkynoxy Moieties as Hydrogen-Accepting Directing Groups

Ruthenium-Catalyzed meta-Selective C-H Bromination - Teskey

Zinc-Catalyzed Dual C–X and C–H Borylation of Aryl Halides - Bose

DOI: 10.1002/anie.201505603

Ruthenium-Catalyzed Oxidant-Free Allylation of Aromatic Ketoximes with Allylic Acetates at Room Temperature

DOI: 10.1002/chem.201502284

Microwave-assisted, ruthenium-catalyzed intramolecular amide-alkyne annulation for the rapid synthesis of fused tricyclic isoquinolinones

Copper-Catalyzed Intramolecular Dehydrogenative Amidation of Unactivated C(sp3)–H Bonds Using O2 as the Sole Oxidant

Palladium-Catalyzed ortho-Olefination of Phenyl Acetic and Phenyl Propylacetic Esters via C–H Bond Activation

Recyclable and Reusable [RuCl2(p-cymene)]2/Cu(OAc)2/PEG-400/H2O System for Oxidative C–H Bond Alkenylations: Green Synthesis of Phthalides

Pd-Catalyzed Ag(I)-Promoted C3-Arylation of Pyrido[1,2-a]pyrimidin-4-ones with Bromo/Iodo-Arenes

Rh(III)-Catalyzed Trifluoromethylthiolation of Indoles via C–H Activation

Mechanistic Understanding of the Divergent Reactivity of Cyclopropenes in Rh(III)-Catalyzed C–H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and N-Pivaloxybenzamide

Synthesis of Benzofulvene Derivatives from Diarylacetylenes via Pd(II)-Catalyzed Alkyne-Directed C(sp2)–H Bond Activation

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

DOI: 10.1021/acs.chemrev.5b00162

Cobalt(III)-Catalyzed C2-Selective C–H Alkynylation of Indoles

DOI: 10.1021/acs.orglett.5b02038

Mechanistic Insights into the Palladium-Catalyzed Aziridination of Aliphatic Amines by C–H Activation

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling between Heteroaryl Iodides and α-Chloronitriles

DOI: 10.1021/jacs.5b06466

Aminoboration: Addition of B–N σ Bonds across C–C π Bonds

DOI: 10.1021/jacs.5b06678

Frustrated Lewis Pairs

DOI: 10.1021/jacs.5b06794

Enantioselective palladium(0)-catalyzed intramolecular cyclopropane functionalization: access to dihydroquinolones, dihydroisoquinolones and the BMS-791325 ring system

DOI: 10.1039/C5SC01909E

Rh-catalyzed sequential oxidative C–H activation/annulation with geminal-substituted vinyl acetates to access isoquinolines

DOI: 10.1039/C5CC04708K

Copper-Catalyzed Formal [4 + 1] Cycloaddition of Benzamides and Isonitriles via Directed C–H Cleavage

DOI: 10.1021/acs.orglett.5b01986

Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β,β-Disubstituted Enones in Aqueous Media: Formation of Bis-benzylic and ortho-Substituted Benzylic Quaternary Centers

Mechanistic Aspects of the Carboxylative Cyclization of Propargylamines and Carbon Dioxide Catalyzed by Gold(I) Complexes Bearing an N-Heterocyclic Carbene Ligand

Monoselective o-C–H Functionalizations of Mandelic Acid and α-Phenylglycine

DOI: 10.1021/jacs.5b04324

Palladium(II)-Catalyzed Tandem Oxidative Acetoxylation/ortho C–H Activation/Carbocyclization of Arylallenes

Rhodium-Catalyzed [5 + 2 + 1] Cycloaddition of Ene–Vinylcyclopropanes and CO: Reaction Design, Development, Application in Natural Product Synthesis, and Inspiration for Developing New Reactions for Synthesis of Eight-Membered Carbocycles

Half-Sandwich Rare-Earth-Catalyzed Olefin Polymerization, Carbometalation, and Hydroarylation

DOI: 10.1021/acs.accounts.5b00219

Copper-Mediated Oxidative Coupling of Benzamides with Maleimides via Directed C–H Cleavage

Catalyst Controlled Divergent C4/C8 Site-Selective C–H Arylation of Isoquinolones

Palladium-Catalyzed Site-Selective Fluorination of Unactivated C(sp3)–H Bonds

DOI: 10.1021/acs.orglett.5b01710

RhIII-Catalyzed [4 + 1] Annulations of 2-Hydroxy- and 2-Aminobenzaldehydes with Allenes: A Simple Method toward 3-Coumaranones and 3-Indolinones

DOI: 10.1021/acs.orglett.5b01825

Study of Sustainability and Scalability in the Cp*Rh(III)-Catalyzed Direct C–H Amidation with 1,4,2-Dioxazol-5-ones

DOI: 10.1021/acs.oprd.5b00164

Synthesis of N-Sulfonylamidated and Amidated Azobenzenes under Rhodium Catalysis

DOI: 10.1021/acs.joc.5b01149

Transition-Metal-Catalyzed Site-Selective C–H Functionalization of Quinolines beyond C2 Selectivity