The Oxime Portmanteau Motif: Released Heteroradicals Undergo Incisive EPR Interrogation and Deliver Diverse Heterocycles

DOI: 10.1021/ar500017f

Catalytic Enantioselective 1,3-Dipolar Cycloadditions of Azomethine Ylides for Biology-Oriented Synthesis

DOI: 10.1021/ar400286b

The [3 + 3]-Cycloaddition Alternative for Heterocycle Syntheses: Catalytically Generated Metalloenolcarbenes as Dipolar Adducts

DOI: 10.1021/ar5000055

C–H Methylation of Heteroarenes Inspired by Radical SAM Methyl Transferase

DOI: 10.1021/ja5007838

Directing Group-Controlled Regioselectivity in an Enzymatic C–H Bond Oxygenation

DOI: 10.1021/ja5016052

Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C–H Bond Arylation

DOI: 10.1021/ja500444v

Pd-catalyzed dehydrogenative cross-coupling of pyridine-N-oxides with uracils

DOI: 10.1039/C4RA01034E

Design and synthesis of imidazo[1,2-α][1,8]naphthyridine derivatives as anti-HCV agents via direct C–H arylation

DOI: 10.1039/C3OB42525H

Synthesis of Pyrazolo[1,2-a]cinnolines via a Rhodium-Catalyzed Oxidative Coupling Approach

DOI: 10.1002/adsc.201301009

Rhodium(III)-Catalyzed Oxidative Olefination of Picolinamides: Convenient Synthesis of 3-Alkenylpicolinamides

DOI: 10.1002/adsc.201300895

Palladium-Catalyzed Desulfitative Cross-Coupling Reaction of Sodium Arylsulfinates with H-Phosphonate Diesters

DOI: 10.1002/adsc.201300983

Synthesis of Saturated N-Heterocycles

Rhodium-Catalyzed Direct C–H Bond Cyanation of Arenes with Isocyanide

Palladium(II)-Catalyzed Direct Regioselectively Oxidative Acylation of Azobenzenes with Toluene Derivatives

Palladium-catalyzed oxidative C–H/C–H cross-coupling of benzothiazoles with thiophenes and thiazoles

DOI: 10.1039/C4CC00362D

Nickel-catalyzed chelation-assisted direct arylation of unactivated C(sp3)–H bonds with aryl halides

DOI: 10.1039/C4CC00716F

Visible-Light-Promoted Radical C–H Trifluoromethylation of Free Anilines

DOI: 10.1021/ol500469a

Access to Cinnamyl Derivatives from Arenes and Allyl Esters by a Biomimetic Aerobic Oxidative Dehydrogenative Coupling

DOI: 10.1021/ol500326g

Palladium-Catalyzed C-2 Selective Olefination of Thiazoles

DOI: 10.1021/ol500542j

Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2-Allyl-3-iodoindoles and Terminal Alkynes

DOI: 10.1021/ol500119r

Cross-Coupling Hydrogen Evolution Reaction in Homogeneous Solution without Noble Metals

DOI: 10.1021/ol500534w

Orthogonal Reactivity of Acyl Azides in C–H Activation: Dichotomy between C–C and C–N Amidations Based on Catalyst Systems

DOI: 10.1021/ol500602b

Palladium Catalyzed Direct C-2 Arylation of Indoles

10.1016/j.jorganchem.2014.02.017

Synthesis of Substituted Tetrahydron-1H-carbazol-1-one and Analogs via PhI(OCOCF3)2-Mediated Oxidative C-C Bond Formation

DOI: 10.1016/j.tet.2014.02.083

The First Example of Nickel-Catalyzed Silyl-Heck Reactions: Direct Activation of Silyl Triflates Without Iodide Additives

10.1016/j.tet.2014.03.021

Iridium-Catalyzed C–H Borylation of Heteroarenes: Scope, Regioselectivity, Application to Late-Stage Functionalization, and Mechanism

DOI: 10.1021/ja412563e

Cobalt-Catalyzed C–H Borylation

DOI: 10.1021/ja500712z

Overriding Ortho–Para Selectivity via a Traceless Directing Group Relay Strategy: The Meta-Selective Arylation of Phenols

DOI: 10.1021/ja500457s

Hydroarylation of Arynes Catalyzed by Silver for Biaryl Synthesis

DOI: 10.1021/ja500292x

Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes

DOI: 10.1021/ja412881j

Palladium-Catalyzed Intramolecular Asymmetric C–H Functionalization/Cyclization Reaction of Metallocenes: An Efficient Approach toward the Synthesis of Planar Chiral Metallocene Compounds

DOI: 10.1021/ja500699x

Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance

Electrophilic alkynylation of ketones using hypervalent iodine

DOI: 10.1039/C4CC00608A

Ligand promoted Pd-catalyzed dehydrogenative alkenylation of hetereoarenes

DOI: 10.1039/C3CC48750D

PdCl2 catalyzed efficient assembly of organic azides, CO, and alcohols under mild conditions: a direct approach to synthesize carbamates

DOI: 10.1039/C4CC00538D

Iridium-catalyzed ortho-C–H borylation of aromatic aldimines derived from pentafluoroaniline with bis(pinacolate)diboron

DOI: 10.1039/C3OB42497A

Direct sp3 C–H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis with nucleophilic catalysis

DOI: 10.1039/C3OB42453G

C2-Arylation of Substituted Pyridine N-oxides with Heteroaryl Carboxylic Acids by Palladium-Catalyzed Decarboxylative Coupling

DOI: 10.1002/ajoc.201400013

Dimeric Pd(II) and Pt(II) chloride organometallics with 2-phenylpyridine and their solvolysis in dimethylsulfoxide

Recent Applications of C 1-Symmetric Bis(oxazoline)-Containing Ligands in Asymmetric Catalysis

DOI: 10.1055/s-0033-1340829

Synthesis of benzo-γ-sultams via the Rh-catalyzed aromatic C–H functionalization of diazosulfonamides

DOI: 10.1039/C4CC00250D

Copper-catalysed oxidative C–H/C–H coupling between olefins and simple ethers

DOI: 10.1039/C4CC00867G

Iron-catalyzed/mediated oxidative transformation of C–H bonds

DOI: 10.1039/C3QO00087G

Palladium-catalyzed benzo[d]isoxazole synthesis by C–H activation/[4 + 1] annulation

DOI: 10.1039/C3SC53228C

Selective thienylation of fluorinated benzothiadiazoles and benzotriazoles for organic photovoltaics

DOI: 10.1039/C3SC53119H

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

DOI: 10.1039/C3SC53076K

Applications of C–H Functionalization Logic to Cyclobutane Synthesis

Competition between sp3-C–N vs sp3-C–F Reductive Elimination from PdIV Complexes

DOI: 10.1021/ja411433f

One-Pot, Single-Step, and Gram-Scale Synthesis of Mononuclear [(η6-arene)Ni(N-heterocyclic carbene)] Complexes: Useful Precursors of the Ni0–NHC Unit

DOI: 10.1021/om500088p

Mechanistic Investigations of Palladium-Catalyzed Allylic Fluorination

DOI: 10.1021/om401240p