Raji Chem World

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Friday, May 30, 2014

Ruthenium catalysed C–H bond borylation

Graphical abstract: Ruthenium catalysed C–H bond borylation
DOI: 10.1039/C4CC02096K

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Rhodium(iii)-catalyzed formal oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters. A facile synthesis of functionalized benzolactams

Graphical abstract: Rhodium(iii)-catalyzed formal oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters. A facile synthesis of functionalized benzolactams
DOI: 10.1039/C4OB00512K
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Thursday, May 29, 2014

Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes

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Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

Graphical abstract: Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

DOI: 10.1039/C4CC02060J
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Wednesday, May 28, 2014

Catalytic Cycle for Palladium-Catalyzed Decarbonylative Trifluoromethylation using Trifluoroacetic Esters as the CF3 Source

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Tuesday, May 27, 2014

Direct Metal-Catalyzed Regioselective Functionalization of Enamides

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DOI: 10.1002/chem.201402070
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Monday, May 26, 2014

Synthesis of Indolo[2,1-a]isoquinolines via a Triazene-Directed C–H Annulation Cascade

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DOI: 10.1021/jo500807d
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Rh(III)-Catalyzed Cascade Oxidative Olefination/Cyclization of Picolinamides and Alkenes via C–H Activation

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DOI: 10.1021/ol501275r
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Transition-Metal-Free Semihydrogenation of Diarylalkynes: Highly Stereoselective Synthesis of trans-Alkenes Using Na2S·9H2O

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DOI: 10.1021/ol501137x
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Phosphaannulation by Palladium-Catalyzed Carbonylation of C–H Bonds of Phosphonic and Phosphinic Acids

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DOI: 10.1021/ol501066k
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Copper-Mediated Tandem Oxidative C(sp2)–H/C(sp)–H Alkynylation and Annulation of Arenes with Terminal Alkynes

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DOI: 10.1021/ol501023n
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Friday, May 23, 2014

Rhodium(iii)-catalyzed C2-selective carbenoid functionalization and subsequent C7-alkenylation of indoles

Graphical abstract: Rhodium(iii)-catalyzed C2-selective carbenoid functionalization and subsequent C7-alkenylation of indoles
DOI: 10.1039/C4CC01593B
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tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp3)–H/C(sp2)–H bond functionalization

Graphical abstract: tert-Butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane: efficient synthesis of 6-alkyl phenanthridines via C(sp3)–H/C(sp2)–H bond functionalization
DOI: 10.1039/C4CC00743C
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Thursday, May 22, 2014

Recent Advances in Palladium-Catalyzed C(sp3)–H Activation for the Formation of Carbon–Carbon and Carbon–Heteroatom Bonds

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Wednesday, May 21, 2014

Reductive Cross-Coupling Reactions between Two Electrophiles

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DOI: 10.1002/chem.201402302
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Nickel-Catalyzed Decarboxylative Acylation of Heteroarenes by sp2 C[BOND]H Functionalization

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DOI: 10.1002/chem.201402516
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Room-Temperature ortho-Alkoxylation and -Halogenation of N-Tosylbenzamides by Using Palladium(II)-Catalyzed C[BOND]H Activation

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DOI: 10.1002/chem.201303923
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Synthesis of Dibenzothiophenes by Pd-Catalyzed Dual C[BOND]H Activation from Diaryl Sulfides

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DOI: 10.1002/chem.201402265
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Ru-Catalyzed Branched versus Linear Selective C3-Alkylation of 2-Aroylbenzofurans with Acrylates via C[BOND]H Activation

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DOI: 10.1002/chem.201400401
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Tuesday, May 20, 2014

Iridium-catalysed borylation of sterically hindered C(sp3)–H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide

Graphical abstract: Iridium-catalysed borylation of sterically hindered C(sp3)–H bonds: remarkable rate acceleration by a catalytic amount of potassium tert-butoxide
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Monday, May 19, 2014

Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species

Graphical abstract: Regioselective transformation of alkynes catalyzed by a copper hydride or boryl copper species
DOI: 10.1039/C4CY00070F
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Cu(i)-catalyzed chemical fixation of CO2 with 2-alkynylaniline into 4-hydroxyquinolin-2(1H)-one

Graphical abstract: Cu(i)-catalyzed chemical fixation of CO2 with 2-alkynylaniline into 4-hydroxyquinolin-2(1H)-one
DOI: 10.1039/C3CY00858D
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Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines

Graphical abstract: Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines
DOI: 10.1039/C4CY00130C
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Homogeneous hydrogenation of carbon dioxide to methanol

Graphical abstract: Homogeneous hydrogenation of carbon dioxide to methanol
DOI: 10.1039/C3CY00564J
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Recent progress in catalytic conversions of carbon dioxide

Graphical abstract: Recent progress in catalytic conversions of carbon dioxide
DOI: 10.1039/C3CY00993A
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Catalytic conversion and use of carbon dioxide

Graphical abstract: Catalytic conversion and use of carbon dioxide
DOI: 10.1039/C4CY90014F


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Synthesis of 2-Aryl-2H-benzotrizoles from Azobenzenes and N-Sulfonyl Azides through Sequential Rhodium-Catalyzed Amidation and Oxidation in One Pot

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DOI: 10.1021/ol501250t
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Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp3)–H Functionalization

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DOI: 10.1021/jo5008515
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Recent Advances in the Stereoselective Synthesis of Aziridines

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DOI: 10.1021/cr400553c

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Phthalides and Phthalans: Synthetic Methodologies and Their Applications in the Total Synthesis

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DOI: 10.1021/cr400524q
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Friday, May 16, 2014

Rh(iii)-catalyzed regioselective hydroarylation of alkynes via directed C–H functionalization of pyridines

Graphical abstract: Rh(iii)-catalyzed regioselective hydroarylation of alkynes via directed C–H functionalization of pyridines
DOI: 10.1039/C4OB00612G
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Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide

Graphical abstract: Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide
DOI: 10.1039/C4OB00590B
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Thursday, May 15, 2014

Rh(iii)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water

Graphical abstract: Rh(iii)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water
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Tuesday, May 13, 2014

Palladium-Catalyzed Intermolecular Allylic Dearomatization Reaction of α-Substituted β-Naphthol Derivatives: Scope and Mechanistic Investigation

DOI: 10.1002/adsc.201400154
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Synthesis of Biaryls through Aromatic C[BOND]H Bond Activation: A Review of Recent Developments

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Monday, May 12, 2014

Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds

Graphical abstract: Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds
DOI: 10.1039/C3SC53115E
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Catalytic enantioselective synthesis of 2-aryl-chromenes

Graphical abstract: Catalytic enantioselective synthesis of 2-aryl-chromenes
DOI: 10.1039/C4SC00423J
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Pd(quinox)-catalyzed allylic relay Suzuki reactions of secondary homostyrenyl tosylates via alkene-assisted oxidative addition

Graphical abstract: Pd(quinox)-catalyzed allylic relay Suzuki reactions of secondary homostyrenyl tosylates via alkene-assisted oxidative addition
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Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and Rh

Graphical abstract: Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and Rh
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A catalyst-controlled selective synthesis of pyridines and pyrroles

Graphical abstract: A catalyst-controlled selective synthesis of pyridines and pyrroles
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Non-directed allylic C–H acetoxylation in the presence of Lewis basic heterocycles

Graphical abstract: Non-directed allylic C–H acetoxylation in the presence of Lewis basic heterocycles
DOI: 10.1039/C3SC53414F
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Copper catalyzed direct alkenylation of simple alkanes with styrenes

Graphical abstract: Copper catalyzed direct alkenylation of simple alkanes with styrenes
DOI: 10.1039/C4SC00093E
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Synthesis of Carbazoles by Copper-Catalyzed Intramolecular C–H/N–H Coupling

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DOI: 10.1021/ol501037j
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Aerobic Oxidative C–H Olefination of Cyclic N-Sulfonyl Ketimines Catalyzed by a Rhodium Catalyst

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DOI: 10.1021/ol501152a
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Palladium-Catalyzed C(sp2)–H Pyridocarbonylation of N-Aryl-2-aminopyridines: Dual Function of the Pyridyl Moiety

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DOI: 10.1021/ol501070g
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Highly Site-Selective Direct C–H Bond Functionalization of Phenols with α-Aryl-α-diazoacetates and Diazooxindoles via Gold Catalysis

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DOI: 10.1021/ja503163k
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Saturday, May 10, 2014

Alkene-Assisted Nickel-Catalyzed Regioselective 1,4-Addition of Organoboronic Acid to Dienones: A Direct Route to All-Carbon Quaternary Centers

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DOI: 
10.1021/ol500838h
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Friday, May 9, 2014

sp3C–H bond alkylation of ketones with alkenes via ruthenium(ii) catalysed dehydrogenation of alcohols

Graphical abstract: sp3C–H bond alkylation of ketones with alkenes via ruthenium(ii) catalysed dehydrogenation of alcohols
DOI: 10.1039/C4CC00931B
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Thursday, May 8, 2014

Palladium-catalyzed direct ortho-C–H ethoxycarboxylation of anilides at room temperature

Graphical abstract: Palladium-catalyzed direct ortho-C–H ethoxycarboxylation of anilides at room temperature
10.1039/C3QO00069A
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Tuesday, May 6, 2014

Iron-Catalyzed Synthesis of Heterocycles

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