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Tuesday, December 30, 2014

Direct amidation of the phenylalanine moiety in short peptides via Pd-catalyzed C–H activation/C–N formation

Graphical abstract: Direct amidation of the phenylalanine moiety in short peptides via Pd-catalyzed C–H activation/C–N formation
DOI: 10.1039/C4QO00282B
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Monday, December 29, 2014

Cobalt(III)-Catalyzed Synthesis of Indazoles and Furans by C–H Bond Functionalization/Addition/Cyclization Cascades

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DOI: 10.1021/ja5116452
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Copper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of Heterocycles

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DOI: 10.1021/cr500410y
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Palladium-Catalyzed ortho-Sulfonylation of 2-Aryloxypyridines and Subsequent Formation of ortho-Sulfonylated Phenols

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DOI: 10.1021/jo5026095
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Synthesis of Benzofused Five-Ring Sultams via Rh-Catalyzed C–H Olefination Directed by an N-Ac-Substituted Sulfonamide Group

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DOI: 10.1021/jo502224d
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Silver-Catalyzed C(sp2)–H Functionalization/C–O Cyclization Reaction at Room Temperature

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DOI: 10.1021/jo5024238
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RhIII-Catalyzed Redox-Neutral C–H Activation of Pyrazolones: An Economical Approach for the Synthesis of N-Substituted Indoles

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DOI: 10.1021/ol503404p
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Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide

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DOI: 10.1021/ol5034018
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Thursday, December 25, 2014

From Anilines to Isatins: Oxidative Palladium-Catalyzed Double Carbonylation of C[BOND]H Bonds

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DOI: 10.1002/anie.201410321
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Tuesday, December 23, 2014

Palladium(ii)-catalyzed meta-selective direct arylation of O-β-naphthyl carbamate

Graphical abstract: Palladium(ii)-catalyzed meta-selective direct arylation of O-β-naphthyl carbamate
DOI: 10.1039/C4CC07997C
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Monday, December 22, 2014

Pd-Catalyzed Monoselective ortho-C–H Alkylation of N-Quinolyl Benzamides: Evidence for Stereoretentive Coupling of Secondary Alkyl Iodides

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DOI: 10.1021/ja511557h
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Palladium-Catalyzed ortho-Selective C–H Fluorination of Oxalyl Amide-Protected Benzylamines

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DOI: 10.1021/jo502365b
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Rhodium(III)-Catalyzed Hydrazine-Directed C–H Activation for Indole Synthesis: Mechanism and Role of Internal Oxidant Probed by DFT Studies

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DOI: 10.1021/om501130c
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Computational Mechanistic Study of Palladium(II)-Catalyzed Carboxyalkynylation of an Olefin Using an Iodine(III) Oxidant Reagent

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DOI: 10.1021/om5011758
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Pd-Catalyzed Dehydrogenative Aryl–Aryl Bond Formation via Double C(sp2)–H Bond Activation: Efficient Synthesis of [3,4]-Fused Oxindoles

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DOI: 10.1021/ol503442n
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Palladium-Catalyzed Synthesis of Six-Membered Benzofuzed Phosphacycles via Carbon–Phosphorus Bond Cleavage

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Silver-Catalyzed C–H Trifluoromethylation of Arenes Using Trifluoroacetic Acid as the Trifluoromethylating Reagent

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DOI: 10.1021/ol503189j
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Rh(III)-Catalyzed Selenylation of Arenes with Selenenyl Chlorides/Diselenides via C–H Activation

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DOI: 10.1021/ol503231
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Cobalt-Catalyzed Enantioselective Directed C–H Alkylation of Indole with Styrenes

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DOI: 10.1021/ol503119z
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Friday, December 19, 2014

Palladium-catalyzed benzothieno[2,3-b]indole formation via dehydrative–dehydrogenative double C–H sulfuration using sulfur powder, indoles and cyclohexanones

Graphical abstract: Palladium-catalyzed benzothieno[2,3-b]indole formation via dehydrative–dehydrogenative double C–H sulfuration using sulfur powder, indoles and cyclohexanones
DOI: 10.1039/C4CC08370A
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Thursday, December 18, 2014

Palladium-catalyzed unactivated β-methylene C(sp3)–H bond alkenylation of aliphatic amides and its application in a sequential C(sp3)–H/C(sp2)–H bond alkenylation

Graphical abstract: Palladium-catalyzed unactivated β-methylene C(sp3)–H bond alkenylation of aliphatic amides and its application in a sequential C(sp3)–H/C(sp2)–H bond alkenylation
DOI: 10.1039/C4OB02389G
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Rhodium(III)-Catalyzed Cyclative Capture Approach to Diverse 1-Aminoindoline Derivatives at Room Temperature

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DOI: 10.1002/anie.201410342
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Combined Experimental and Computational Investigations of Rhodium-Catalysed C[BOND]H Functionalisation of Pyrazoles with Alkenes

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DOI: 10.1002/chem.201405550
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Wednesday, December 17, 2014

Enantioselective synthesis of arylglycine derivatives by direct C–H oxidative cross-coupling

Graphical abstract: Enantioselective synthesis of arylglycine derivatives by direct C–H oxidative cross-coupling
DOI: 10.1039/C4CC07361D
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Monday, December 15, 2014

Co(III)-Catalyzed C–H Activation/Formal SN-Type Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation

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DOI: 10.1021/ja511011m
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Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

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DOI: 10.1021/ja509077a
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Ir(III)-Catalyzed Aromatic C–H Bond Functionalization via Metal Carbene Migratory Insertion

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DOI: 10.1021/jo5023102
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The Palladium-Catalyzed Intermolecular C–H Chalcogenation of Arenes

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DOI: 10.1021/jo502402d
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Friday, December 12, 2014

One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

Graphical abstract: One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization
DOI: 10.1039/C4CC08407A

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A nickel-mediated oxidative α-C(sp3)–H functionalization of amides with allylic alcohols terminated by radical 1,2-aryl migration

Graphical abstract: A nickel-mediated oxidative α-C(sp3)–H functionalization of amides with allylic alcohols terminated by radical 1,2-aryl migration
DOI: 10.1039/C4CC08797F

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Rh(iii)-catalyzed oxidative C–H bond arylation with hydroquinones: sustainable synthesis of dibenzo[b,d]pyran-6-ones and benzo[d]naphtho[1,2-b]pyran-6-ones

Graphical abstract: Rh(iii)-catalyzed oxidative C–H bond arylation with hydroquinones: sustainable synthesis of dibenzo[b,d]pyran-6-ones and benzo[d]naphtho[1,2-b]pyran-6-ones

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Thursday, December 11, 2014

Pd(ii)-catalyzed C–H arylation of aryl and benzyl Weinreb amides

Graphical abstract: Pd(ii)-catalyzed C–H arylation of aryl and benzyl Weinreb amides

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A Convenient Synthesis of N-Aryl Benzamides by Rhodium-Catalyzed ortho-Amidation and Decarboxylation of Benzoic Acids

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Wednesday, December 10, 2014

Enamide Derivatives: Versatile Building Blocks for Highly Functionalized α,β-Substituted Amines

https://www.thieme-connect.de/media/synlett/201420/i_a0628_ga_10-1055_s-0034-1379166.gif

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Monday, December 8, 2014

Tandem Catalysis: Rh(III)-Catalyzed C–H Allylation/Pd(II)-Catalyzed N-Allylation Toward the Synthesis of Vinyl-Substituted N-Heterocycles

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DOI: 10.1021/cs501601c

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Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl Acetates: Synthesis of 3-Substituted Isocoumarins

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DOI: 10.1021/jo502231y

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Mild Rhodium(III)-Catalyzed C–H Allylation with 4-Vinyl-1,3-dioxolan-2-ones: Direct and Stereoselective Synthesis of (E)-Allylic Alcohols

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DOI: 10.1021/ol503229c

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Facile Synthesis of 6-Acylated Pyrido[2,1-a]isoindoles from 2-Arylpyridines and γ-Substituted tert-Propargyl Alcohols via Rhodium-Catalyzed C–H Bond Activation and β-Carbon Elimination

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DOI: 10.1021/ol503157k

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Modern Carbon–Fluorine Bond Forming Reactions for Aryl Fluoride Synthesis

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DOI: 10.1021/cr500366b

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Cobalt–Bisoxazoline-Catalyzed Asymmetric Kumada Cross-Coupling of Racemic α-Bromo Esters with Aryl Grignard Reagents

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DOI: 10.1021/ja5109084

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Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion

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DOI: 10.1021/ja5105206

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Saturday, December 6, 2014

Rhodium(iii)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates

Graphical abstract: Rhodium(iii)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates
DOI: 10.1039/C4CC07597H

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Wednesday, December 3, 2014

Iron catalysed direct alkylation of amines with alcohols

Catalytic, direct N-alkylation of amines with alcohols.
doi:10.1038/ncomms6602

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Tuesday, December 2, 2014

Stoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C(sp2)–H arylation

Graphical abstract: Stoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C(sp2)–H arylation
DOI: 10.1039/C4SC02070G
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Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Graphical abstract: Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones
DOI: 10.1039/C4SC02590C
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Mechanistic insights into hydroacylation with non-chelating aldehydes

Graphical abstract: Mechanistic insights into hydroacylation with non-chelating aldehydes
DOI: 10.1039/C4SC02026J
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Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis

Graphical abstract: Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis
DOI: 10.1039/C4SC02591A
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Monday, December 1, 2014

Palladium(II)-Catalyzed Oxidative Dearomatization of Free Naphthols with Two Alkyne Units

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DOI: 10.1021/ol502997d
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B(C6F5)3-Catalyzed Synthesis of Benzofused-Siloles

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DOI: 10.1021/om501033p
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Palladium-Catalyzed C8-Selective C–H Arylation of Quinoline N-Oxides: Insights into the Electronic, Steric, and Solvation Effects on the Site Selectivity by Mechanistic and DFT Computational Studies

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10.1021/cs501813v
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