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Friday, January 30, 2015

Rhodium(iii)-catalyzed C7-position C–H alkenylation and alkynylation of indolines

Graphical abstract: Rhodium(iii)-catalyzed C7-position C–H alkenylation and alkynylation of indolines
DOI: 10.1039/C4CC09330E
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Synthesis of spiroindanes by palladium-catalyzed oxidative annulation of non- or weakly activated 1,3-dienes involving C–H functionalization

Graphical abstract: Synthesis of spiroindanes by palladium-catalyzed oxidative annulation of non- or weakly activated 1,3-dienes involving C–H functionalization
DOI: 10.1039/C4CC09496D
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Rhodium-Catalyzed Desulfination of Sodium Arenesulfinates and Oxidative Annulation with Alkynes

DOI: 10.1002/adsc.201400930
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Wednesday, January 28, 2015

Palladium catalyzed ortho-halogenation of 2-arylbenzothiazole and 2,3-diarylquinoxaline

Graphical abstract: Palladium catalyzed ortho-halogenation of 2-arylbenzothiazole and 2,3-diarylquinoxaline
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Rh(iii)-catalyzed C–H activation/cyclization of benzamides and diazo compounds to form isocoumarins and α-pyrones

Graphical abstract: Rh(iii)-catalyzed C–H activation/cyclization of benzamides and diazo compounds to form isocoumarins and α-pyrones
DOI: 10.1039/C4CC09314C
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Monday, January 26, 2015

Palladium-Catalyzed Carbonylation of Indoles for Synthesis of Indol-3-yl Aryl Ketones

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DOI: 10.1021/cs5019106
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Electrophilic Halogenation–Reductive Elimination Chemistry of Organopalladium and -Platinum Complexes

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DOI: 10.1021/ar500325x
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Rhodium-Catalyzed Borylation of Aryl 2-Pyridyl Ethers through Cleavage of the Carbon–Oxygen Bond: Borylative Removal of the Directing Group

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Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

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DOI: 10.1021/ja511796h
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Mild Rh(III)-Catalyzed C7-Allylation of Indolines with Allylic Carbonates

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DOI: 10.1021/jo502733q
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Palladium-Catalyzed Regioselective Benzylation–Annulation of Pyridine N-Oxides with Toluene Derivatives via Multiple C–H Bond Activations: Benzylation versus Arylation

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DOI: 10.1021/ol503238a
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Assembly of Indoline-2-carboxylate-Embodied Dipeptides via Pd-Catalyzed C(sp2)–H Bond Direct Functionalization

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DOI: 10.1021/ol503514t
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Cobalt-Catalyzed C–H Cyanation of (Hetero)arenes and 6-Arylpurines with N-Cyanosuccinimide as a New Cyanating Agent

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DOI: 10.1021/ol503680d
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Friday, January 23, 2015

Copper(ii)-catalyzed methoxylation of unactivated (hetero)aryl C–H bonds using a removable bidentate auxiliary

Graphical abstract: Copper(ii)-catalyzed methoxylation of unactivated (hetero)aryl C–H bonds using a removable bidentate auxiliary
DOI: 10.1039/C4QO00276H
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Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation

Graphical abstract: Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation
DOI: 10.1039/C4QO00207E
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Direct and Site-Selective Palladium-Catalyzed C-7 Acylation of Indolines with Aldehydes

DOI: 10.1002/adsc.201400942
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Ruthenium(II)-Catalyzed C[BOND]H Arylation of Anilides with Boronic Acids, Borinic Acids and Potassium Trifluoroborates

DOI: 10.1002/adsc.201400906
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Thursday, January 22, 2015

Copper(i)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3 C–H functionalisation

Graphical abstract: Copper(i)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3 C–H functionalisation
DOI: 10.1039/C4OB01962H
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Cu-catalyzed arylation of the amino group in the indazole ring: regioselective synthesis of pyrazolo-carbazoles

Graphical abstract: Cu-catalyzed arylation of the amino group in the indazole ring: regioselective synthesis of pyrazolo-carbazoles
DOI: 10.1039/C4OB02044H
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Ligand-Promoted ortho-C[BOND]H Amination with Pd Catalysts

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DOI: 10.1002/anie.201408651
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Orchestrated Triple C[BOND]H Activation Reactions Using Two Directing Groups: Rapid Assembly of Complex Pyrazoles

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DOI: 10.1002/anie.201410462
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General Method for the Synthesis of Salicylic Acids from Phenols through Palladium-Catalyzed Silanol-Directed C[BOND]H Carboxylation

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DOI: 10.1002/anie.201410375
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RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed C[BOND]C Bond Cleavages

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DOI: 10.1002/chem.20140571
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Iron-Catalyzed Trifluoromethylation of Enamide

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DOI: 10.1002/chem.201406333
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Wednesday, January 21, 2015

Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols

Graphical abstract: Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols
DOI: 10.1039/C4CC09327E
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Tuesday, January 20, 2015

Decarboxylative acylation of arenes with mandelic acid derivatives via palladium-catalyzed oxidative sp2 C–H activation

Graphical abstract: Decarboxylative acylation of arenes with mandelic acid derivatives via palladium-catalyzed oxidative sp2 C–H activation
DOI: 10.1039/C4RA14107E
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Pd-Catalyzed Direct C–H Bond Sulfonylation of Azobenzenes with Arylsulfonyl Chlorides

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DOI: 10.1021/jo502451k
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Iridium(III)-Catalyzed C-7 Selective C–H Alkynylation of Indolines at Room Temperature

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DOI: 10.1021/jo502596k
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Rhodium(III)-Catalyzed Oxidative Alkenylation of 1,3-Dithiane-Protected Arenecarbaldehydes via Regioselective C–H Bond Cleavage

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DOI: 10.1021/ol503722r
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Synthesis of Benzofuro[3,2-b]pyridines via Palladium-Catalyzed Dual C–H Activation of 3-Phenoxypyridine 1-Oxides

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DOI: 10.1021/ol5033464
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Pd-Catalyzed Intramolecular C–N Bond Cleavage, 1,4-Migration, sp3 C–H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand

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DOI: 10.1021/ja512212x
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Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins

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DOI: 10.1021/ja512306a
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Palladium(II)-Catalyzed Intramolecular Tandem Aminoalkylation via Divergent C(sp3)–H Functionalization

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DOI: 10.1021/ja5102739
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Pd(II)-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation

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DOI: 10.1021/ja512029x
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Friday, January 16, 2015

Rhodium(III)-Catalyzed ortho-Arylation of Anilides with Aryl Halides

DOI: 10.1002/adsc.201400798
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Thursday, January 15, 2015

Transition-Metal-Catalyzed π-Bond-Assisted C[BOND]H Bond Functionalization: An Emerging Trend in Organic Synthesis

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DOI: 10.1002/asia.201403224
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Copper catalyzed room temperature lactonization of aromatic C–H bond: a novel and efficient approach for the synthesis of dibenzopyranones

Graphical abstract: Copper catalyzed room temperature lactonization of aromatic C–H bond: a novel and efficient approach for the synthesis of dibenzopyranones
DOI: 10.1039/C4RA13665A
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Tuesday, January 13, 2015

Construction of N-containing heterocycles via oxidative intramolecular N–H/X–H coupling

Graphical abstract: Construction of N-containing heterocycles via oxidative intramolecular N–H/X–H coupling
DOI: 10.1039/C4CC08116A
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Monday, January 12, 2015

The Azomethine Ylide Route to Amine C–H Functionalization: Redox-Versions of Classic Reactions and a Pathway to New Transformations

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DOI: 10.1021/ar5003768
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Robust Ruthenium(II)-Catalyzed C–H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers

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DOI: 10.1021/op500330g
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Iron-Catalyzed Directed C2-Alkylation and Alkenylation of Indole with Vinylarenes and Alkynes

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DOI: 10.1021/ol503395g
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Palladium-Catalyzed Oxidative Carbonylation of Aromatic C–H Bonds of N-Alkylanilines with CO and Alcohols for the Synthesis of o-Aminobenzoates

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DOI: 10.1021/jo502581p
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Cobalt(III)-Catalyzed C–H Amidation of Arenes using Acetoxycarbamates as Convenient Amino Sources under Mild Conditions

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DOI: 10.1021/cs501860b
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Monday, January 5, 2015

Role of Hemilabile Diamine Ligands in the Amine-Directed C–H Borylation of Arenes

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DOI: 10.1021/om5007837
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Practical Route to 2-Quinolinones via a Pd-Catalyzed C–H Bond Activation/C–C Bond Formation/Cyclization Cascade Reaction

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DOI: 10.1021/ol503292p
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