Pd(II)-Catalyzed Direct Sulfonylation of Unactivated C(sp3)–H Bonds with Sodium Sulfinates

Pd(II)-Catalyzed Direct Sulfonylation of Unactivated C(sp3)–H Bonds with Sodium Sulfinates

DOI: 10.1021/acs.orglett.5b01634

Divergent Functionalization of Indoles with Acryloyl Silanes via Rhodium-Catalyzed C–H Activation

DOI: 10.1021/acs.orglett.5b01258

Copper-/Silver-Mediated Arylation of C(sp2)–H Bonds with 2-Thiophenecarboxylic Acids

DOI: 10.1021/acs.orglett.5b0156

Palladium-catalyzed ortho-C–H alkenylation of 2-benzyl-1,2,3-triazoles

DOI: 10.1039/C5OB00973A

RhIII-Catalyzed C(sp3)[BOND]H Bond Activation by an External Base Metalation/Deprotonation Mechanism: A Theoretical Study

DOI: 10.1002/chem.201501539

Cp*RhIII-Catalyzed Arylation of C(sp3)[BOND]H Bonds

DOI: 10.1002/anie.201503888

Efficient Pd0-Catalyzed Asymmetric Activation of Primary and Secondary C–H Bonds Enabled by Modular Binepine Ligands and Carbonate Bases

DOI: 10.1021/acscatal.5b00898

Mild and Efficient One-Pot Synthesis of 2-(Perfluoroalkyl)indoles by Means of Sequential Michael-Type Addition and Pd(II)-Catalyzed Cross-Dehydrogenative Coupling (CDC) Reaction

DOI: 10.1021/acs.orglett.5b01479

Tandem Dehydrogenation/Oxidation/Oxidative Cyclization Approach to Wrightiadione and Its Derivatives

DOI: 10.1021/acs.orglett.5b01618

Synthesis of Dibenzofurans via C–H Activation of o-Iodo Diaryl Ethers

Stereoselective Synthesis of Chiral β-Fluoro α-Amino Acids via Pd(II)-Catalyzed Fluorination of Unactivated Methylene C(sp3)–H Bonds: Scope and Mechanistic Studies

Iron-Catalyzed Directed C(sp2)–H and C(sp3)–H Functionalization with Trimethylaluminum

Preparation of di--chlorobis(1,5-cyclooctadiene)diiridium (I) [Ir(cod)Cl]2

To a 150.0 mL 3-neck flask was added IrCl₃·3H₂O (1.0 g, 3.0 mmol) followed by addition of 95% of ethanol (17.0 mL), water (8.5 mL) and 1,5-cyclooctadiene (3.0 mL, 24.5 mmol) under nitrogen atmosphere. The resulting mixture was stirred under reflux for 24 h and formed a brick red precipitate. It was allowed to cool to room temperature and filtered. The precipitate was rinsed with cold methanol to remove the trace amount of 1,5-cyclooctadiene unreacted. Then the product was dried in vacuum for 8 h. And [Ir(COD)Cl]₂ was obtained in 67% yield as a brick red solid. mp 200–202 °C.

Ruthenium-catalyzed ortho alkenylation of aromatic nitriles with activated alkenes via C–H bond activation

DOI: 10.1039/C5CC03112E

Palladium-catalyzed ortho-acyloxylation of N-nitrosoanilines via direct sp2 C–H bond activation

DOI: 10.1039/C5OB00691K

Palladium-catalyzed direct ortho-sulfonylation of azobenzenes with arylsulfonyl chlorides via C–H activation

DOI: 10.1039/C5RA06474K

Synthesis of Indolo[1,2-a][1,8]naphthyridines by Rhodium(III)-Catalyzed Dehydrogenative Coupling via Rollover Cyclometalation

DOI: 10.1021/acs.orglett.5b01452

Ru-Catalyzed Regioselective CH-Hydroarylation of Alkynes with Benzylthioethers Using Sulfur as Directing Group

DOI: 10.1021/acs.orglett.5b01552

Rhodium(III)-Catalyzed Oxidative Annulation of 7-Azaindoles and Alkynes via Double C–H Activation

DOI: 10.1021/acs.orglett.5b01228

Iodoarene-Catalyzed Stereospecific Intramolecular sp3 C–H Amination: Reaction Development and Mechanistic Insights

DOI: 10.1021/jacs.5b03488

Mechanistic Understanding of the Aryl-Dependent Ring Formations in Rh(III)-Catalyzed C–H Activation/Cycloaddition of Benzamides and Methylenecyclopropanes by DFT Calculations

DOI: 10.1021/acs.organomet.5b00317

Cp*Rh(iii) and Cp*Ir(iii)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

Cp∗Co(III)-catalyzed direct functionalization of aromatic C–H bonds with α-diazomalonates

Palladium-catalyzed dehydrogenative annulation of imidazo[1,2-a]pyridines with diarylalkynes

doi:10.1016/j.tetlet.2015.05.028

Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

DOI: 10.1021/acs.chemrev.5b00138

Cross-Couplings Using Aryl Ethers via C–O Bond Activation Enabled by Nickel Catalysts

10.1021/acs.accounts.5b00051

Manganese Catalyzed C–H Halogenation

DOI: 10.1021/acs.accounts.5b00062

Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands

DOI: 10.1021/acs.accounts.5b00134

Chelating Bis-N-heterocyclic Carbene–Palladium(II) Complexes for Oxidative Arene C–H Functionalization

Ruthenium-catalyzed decarbonylative addition reaction of anhydrides with alkynes: a facile synthesis of isocoumarins and α-pyrones

DOI: 10.1039/C5CC03311J

Pd(ii) catalyzed ortho C–H iodination of phenylcarbamates at room temperature using cyclic hypervalent iodine reagents

DOI: 10.1039/C5CC02533H