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Monday, November 30, 2015

Synthesis of 1,2-Dihydropyridines Catalyzed by Well-Defined Low-Valent Cobalt Complexes: C–H Activation Made Simple

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DOI: 10.1021/acscatal.5b02138
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Para-Selective Halogenation of Nitrosoarenes with Copper(II) Halides

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DOI: 10.1021/acs.orglett.5b03198
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Domino Oxidative [Pd]-Catalysis: One-Pot Synthesis of Fluorenones Starting from Simple Benzylamines and Iodo Arenes

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DOI: 10.1021/acs.orglett.5b03077
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Regioselective Access to Sultam Motifs through Cobalt-Catalyzed Annulation of Aryl Sulfonamides and Alkynes using an 8-Aminoquinoline Directing Group

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DOI: 10.1002/adsc.201500690
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Rhodium(III)-Catalyzed Direct C[BOND]H Olefination of Arenes with Aliphatic Olefins

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DOI: 10.1002/adsc.201500697
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Rhodium(III)-Catalyzed Synthesis of Aryl Spirocycles by Aromatic C[BOND]H Activation/Intramolecular Heck-Type Reaction

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DOI: 10.1002/adsc.201500768
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Organocatalytic Radical Involved Oxidative Cross-Coupling of N-Hydroxyphthalimide with Benzylic and Allylic Hydrocarbons

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DOI: 10.1002/adsc.201500623
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Friday, November 27, 2015

Relayed Regioselective Alkynylation/Olefination of Unsymmetrical Cyclic Diaryliodonium Species Catalyzed by Cu and Pd: Affording Fluorescent Cytotoxic Benzoxazoles

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Recent Progress in Dehydro(genative) Diels–Alder Reaction

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DOI: 10.1002/chem.201503571

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Stereoselective Synthesis of 1,3-Diaminotruxillic Acid Derivatives: An Advantageous Combination of C[BOND]H-ortho-Palladation and On-Flow [2+2]-Photocycloaddition in Microreactors

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DOI: 10.1002/chem.201503742
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A Novel Pd-Catalysed Annulation Reaction for the Syntheses of Pyrroloindoles and Pyrroloquinolines

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DOI: 10.1002/chem.20150365
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Wednesday, November 25, 2015

Molecular iron complexes as catalysts for selective C–H bond oxygenation reactions

Graphical abstract: Molecular iron complexes as catalysts for selective C–H bond oxygenation reactions
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Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis

Graphical abstract: Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis
DOI: 10.1039/C5CC07767B
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Regioselective synthesis of multisubstituted isoquinolones and pyridones via Rh(iii)-catalyzed annulation reactions

Graphical abstract: Regioselective synthesis of multisubstituted isoquinolones and pyridones via Rh(iii)-catalyzed annulation reactions
DOI: 10.1039/C5CC05977A
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Monday, November 23, 2015

Scope of Successive C–H Functionalizations of the Methyl Group in 3-Picolines: Intramolecular Carbonylation of Arenes to the Metal-Free Synthesis of 4-Azafluorenones

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DOI: 10.1021/acs.orglett.5b03071
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Aromaticity-Dependent Regioselectivity in Pd(II)-Catalyzed C–H Direct Arylation of Aryl Ureas

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DOI: 10.1021/acs.orglett.5b03153
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Cascade Synthesis of 3-Alkylidene Dihydrobenzofuran Derivatives via Rhodium(III)-Catalyzed Redox-Neutral C–H Functionalization/Cyclization

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DOI: 10.1021/acs.orglett.5b03060
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Thursday, November 19, 2015

Catalytic Electrophilic C[BOND]H Silylation of Pyridines Enabled by Temporary Dearomatization

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10.1002/anie.201508181
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Zinc-Catalyzed Dehydrogenative Cross-Coupling of Terminal Alkynes with Aldehydes: Access to Ynones

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Reactivity of Gold Complexes towards Elementary Organometallic Reactions

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DOI: 10.1002/anie.201506271
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Regioselective palladium(ii)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins

Graphical abstract: Regioselective palladium(ii)-catalyzed aerobic oxidative Heck-type C3 alkenylation of sulfocoumarins
DOI: 10.1039/C5QO00294J
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Photocatalytic fluoroalkylation reactions of organic compounds

Graphical abstract: Photocatalytic fluoroalkylation reactions of organic compounds
DOI: 10.1039/C5OB01486G
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Metal-free methylation of a pyridine N-oxide C–H bond by using peroxides

Graphical abstract: Metal-free methylation of a pyridine N-oxide C–H bond by using peroxides
DOI: 10.1039/C5OB01900A
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Synthesis of indoles and polycyclic amides via ruthenium(ii)-catalyzed C–H activation and annulation

Graphical abstract: Synthesis of indoles and polycyclic amides via ruthenium(ii)-catalyzed C–H activation and annulation
DOI: 10.1039/C5OB01788B
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Oxygen-Promoted Suzuki–Miyaura Reaction for Efficient Construction of Biaryls

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DOI: 10.1002/tcr.201500218
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Monday, November 16, 2015

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

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DOI: 10.1021/cr500431s
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Copper-Mediated Remote C–H Bond Chalcogenation of Quinolines on the C5 Position

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DOI: 10.1021/acs.orglett.5b02511
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Mechanism of Intramolecular Rhodium- and Palladium-Catalyzed Alkene Alkoxyfunctionalizations

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DOI: 10.1021/acs.organomet.5b00749
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Rhodium(III)-Catalyzed Direct Cyanation of Aromatic C–H Bond to Form 2-(Alkylamino)benzonitriles Using N-Nitroso As Directing Group

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DOI: 10.1021/acs.joc.5b01666
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Palladium-Catalyzed Direct Arylation of C(sp3)–H Bonds of α-Cyano Aliphatic Amides

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DOI: 10.1021/acs.joc.5b02138
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Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes

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Cobalt- and Nickel-Catalyzed Carboxylation of Alkenyl and Sterically Hindered Aryl Triflates Utilizing CO2

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DOI: 10.1021/acs.joc.5b02307
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Sulfate Radical Anion (SO4•–) Mediated C(sp3)–H Nitrogenation/Oxygenation in N-Aryl Benzylic Amines Expanded the Scope for the Synthesis of Benzamidine/Oxazine Heterocycles

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DOI: 10.1021/acs.joc.5b01872
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Copper-Catalyzed Cross-Dehydrogenative C–N Bond Formation of Azines with Azoles: Overcoming the Limitation of Oxidizing N–O Activation Strategy

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Saturday, November 14, 2015

The Applications of (Para)formaldehyde in Metal-Catalyzed Organic Synthesis

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DOI: 10.1002/adsc.201500753
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Friday, November 13, 2015

Halogen-Adjusted Chemoselective Synthesis of Fluorene Derivatives with Position-Controlled Substituents

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Rhodium(III)-catalyzed Intramolecular Ar–H/Ar–H Coupling Directed by Carboxylic Group to Produce Dibenzofuran Carboxylic Acids

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The Renaissance and Bright Future of Synthetic Aryne Chemistry

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Directed meta-Selective Bromination of Arenes with Ruthenium Catalysts

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DOI: 10.1002/anie.201507100
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Quinone-Catalyzed Selective Oxidation of Organic Molecules

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DOI: 10.1002/anie.201505017
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Selective Alkenylation and Hydroalkenylation of Enol Phosphates through Direct C[BOND]H Functionalization

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DOI: 10.1002/anie.201506437
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A [4+1] Cyclative Capture Approach to 3H-Indole-N-oxides at Room Temperature by Rhodium(III)-Catalyzed C[BOND]H Activation

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Tunable Cascade Reactions of Alkynols with Alkynes under Combined Sc(OTf)3 and Rhodium Catalysis

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DOI: 10.1002/anie.201508914
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On the Triple Role of Fluoride Ions in Palladium-Catalyzed Stille Reactions

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DOI: 10.1002/chem.201503309
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Palladium(0)/NHC-Catalyzed Reductive Heck Reaction of Enones: A Detailed Mechanistic Study

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DOI: 10.1002/chem.201503217
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Hypervalent Activation as a Key Step for Dehydrogenative ortho C[BOND]C Coupling of Iodoarenes

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DOI: 10.1002/chem.201503987
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Thursday, November 12, 2015

Iodine(iii)-mediated construction of the dibenzoxazepinone skeleton from 2-(aryloxy)benzamides through oxidative C–N formation

Graphical abstract: Iodine(iii)-mediated construction of the dibenzoxazepinone skeleton from 2-(aryloxy)benzamides through oxidative C–N formation
DOI: 10.1039/C5RA20258B
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Rhodium(iii)-catalyzed annulation of arenes with alkynes assisted by an internal oxidizing N–O bond

Graphical abstract: Rhodium(iii)-catalyzed annulation of arenes with alkynes assisted by an internal oxidizing N–O bond
DOI: 10.1039/C5OB01886B
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Wednesday, November 11, 2015

Linear scaling relationships and volcano plots in homogeneous catalysis – revisiting the Suzuki reaction

Graphical abstract: Linear scaling relationships and volcano plots in homogeneous catalysis – revisiting the Suzuki reaction
DOI: 10.1039/C5SC02910D
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C–H arylation and alkenylation of imidazoles by nickel catalysis: solvent-accelerated imidazole C–H activation

Graphical abstract: C–H arylation and alkenylation of imidazoles by nickel catalysis: solvent-accelerated imidazole C–H activation
DOI: 10.1039/C5SC02942B
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