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Monday, January 25, 2016

Palladium(II)-Catalyzed, Heteroatom-Directed, Regioselective C–H Nitration of Anilines Using Pyrimidine as a Removable Directing Group

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DOI: 10.1021/acs.orglett.5b03493
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Cross-Coupling Hydrogen Evolution by Visible Light Photocatalysis Toward C(sp2)–P Formation: Metal-Free C–H Functionalization of Thiazole Derivatives with Diarylphosphine Oxides

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DOI: 10.1021/acs.orglett.5b03497
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N-Iodosuccinimide-Promoted Hofmann–Löffler Reactions of Sulfonimides under Visible Light

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DOI: 10.1021/acs.orglett.5b03476
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Copper-Catalyzed Regioselective C–H Sulfonylation of 8-Aminoquinolines

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DOI: 10.1021/acs.joc.5b02509
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Pd/C-Catalyzed Aminocarbonylation of Aryl Iodides via Oxidative C–N Bond Activation of Tertiary Amines to Tertiary Amides

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DOI: 10.1021/acs.joc.5b02385
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Regioselective Electrophilic Fluorination of Rationally Designed Imidazole Derivatives

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DOI: 10.1021/acs.joc.5b02592
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Metal-Catalyzed Directed Regio- and Enantioselective Ring-Opening of Epoxides

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DOI: 10.1021/acs.accounts.5b00428
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Monday, January 18, 2016

Access to Different Isomeric Dibenzoxazepinones through Copper-Catalyzed C–H Etherification and C–N Bond Construction with Controllable Smiles Rearrangement

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DOI: 10.1021/acs.orglett.5b03378
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Ruthenium Catalyzed Intramolecular C–S Coupling Reactions: Synthetic Scope and Mechanistic Insight

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DOI: 10.1021/acs.orglett.5b03185
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Palladium-Catalyzed Regioselective Arylation of Pyrazolo[1,5-a]pyridines via C–H Activation and Synthetic Applications on P38 Kinase Inhibitors

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DOI: 10.1021/acs.organomet.5b00988
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C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis

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Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp3)–C(sp2) Cross-Coupling

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DOI: 10.1021/acscatal.5b02204
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Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts

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DOI: 10.1021/jacs.5b11441
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One Photocatalyst, n Activation Modes Strategy for Cascade Catalysis: Emulating Coumarin Biosynthesis with (−)-Riboflavin

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DOI: 10.1021/jacs.5b12081

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Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C–H Bonds

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DOI: 10.1021/jacs.5b12153
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Metal-Free CH–CH-Type Cross-Coupling of Arenes and Alkynes Directed by a Multifunctional Sulfoxide Group

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DOI: 10.1021/jacs.5b12579
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Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

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DOI: 10.1021/jacs.5b11311
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Saturday, January 16, 2016

Iodine-Mediated Synthesis of Aromatic Thioethers with Aromatic Amines and Sulfonyl Hydrazides in High Regioselectivity via C(sp2)-H Bond Functionalization

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Catalytic Aerobic Photo-oxidation of a Methyl Group on a Heterocycle to Produce an Aldehyde via Homolytic C[BOND]I Bond Cleavage caused by Irradiation with Visible Light

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Iridium(III)-Catalyzed Direct C-H Sulfonamidation of 2-Aryl-1,2,3-triazole N-Oxides with Sulfonyl Azides

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Palladium-Catalyzed Selective C[BOND]H Activation: A Simple Method to Synthesize C-3 Site Arylated Quinoline Derivatives

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DOI: 10.1002/adsc.201500763
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Friday, January 15, 2016

Synthesis of N-Containing Heterocyclic Compounds Using Visible-light Photoredox Catalysis

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DOI: 10.1002/tcr.201500228
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Cobalt(iii) catalyzed C-8 selective C–H and C–O coupling of quinoline N-oxide with internal alkynes via C–H activation and oxygen atom transfer

Graphical abstract: Cobalt(iii) catalyzed C-8 selective C–H and C–O coupling of quinoline N-oxide with internal alkynes via C–H activation and oxygen atom transfer
DOI: 10.1039/C5CC08736H
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Copper mediated decarboxylative direct C–H arylation of heteroarenes with benzoic acids

Graphical abstract: Copper mediated decarboxylative direct C–H arylation of heteroarenes with benzoic acids
DOI: 10.1039/C5CC08367B
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Photocatalyst-free hypervalent iodine reagent catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids driven by visible-light irradiation

Graphical abstract: Photocatalyst-free hypervalent iodine reagent catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids driven by visible-light irradiation
DOI: 10.1039/C5CC08253F
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Iron(ii) triflate/N-heterocyclic carbene-catalysed cross-coupling of arylmagnesiums with aryl chlorides and tosylates

Graphical abstract: Iron(ii) triflate/N-heterocyclic carbene-catalysed cross-coupling of arylmagnesiums with aryl chlorides and tosylates
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Visible light-promoted C–H functionalization of ethers and electron-deficient arenes

Graphical abstract: Visible light-promoted C–H functionalization of ethers and electron-deficient arenes
DOI: 10.1039/C5CC08817H
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Chemo- and Regioselective Ethynylation of Tryptophan-Containing Peptides and Proteins

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DOI: 10.1002/chem.201504462
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Direct Synthesis of Protoberberine Alkaloids by Rh-Catalyzed C[BOND]H Bond Activation as the Key Step

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DOI: 10.1002/chem.201504378
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Copper-Catalyzed 8-Amido Chelation-Induced Remote C[BOND]H Amination of Quinolines

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DOI: 10.1002/chem.201504207
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Merging Visible-Light Photocatalysis and Palladium Catalysis for C[BOND]H Acylation of Azo- and Azoxybenzenes with α-Keto Acids

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DOI: 10.1002/chem.201504530
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Enantioselective Access to Spirocyclic Sultams by Chiral Cpx–Rhodium(III)-Catalyzed Annulations

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DOI: 10.1002/chem.201504998
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Identifying a Highly Active Copper Catalyst for KA2 Reaction of Aromatic Ketones

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DOI: 10.1002/chem.201504823
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One-Pot Sequential Propargylation/Cycloisomerization: A Facile [4+2]-Benzannulation Approach to Carbazoles

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DOI: 10.1002/chem.201503496
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Monday, January 11, 2016

Nickel N-Heterocyclic Carbene-Catalyzed C–Heteroatom Bond Formation, Reduction, and Oxidation: Reactions and Mechanistic Aspects

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DOI: 10.1021/acscatal.5b02021
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Mechanism of the Visible Light-Mediated Gold-Catalyzed Oxyarylation Reaction of Alkenes

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DOI: 10.1021/acscatal.5b01971
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Mechanism and Origins of Ligand-Controlled Linear Versus Branched Selectivity of Iridium-Catalyzed Hydroarylation of Alkenes

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DOI: 10.1021/acscatal.5b02201
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Factors Controlling Stability and Reactivity of Dimeric Pd(II) Complexes in C–H Functionalization Catalysis

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DOI: 10.1021/acscatal.5b02447
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Oxazolinyl-Assisted C–H Amidation by Cobalt(III) Catalysis

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DOI: 10.1021/acscatal.5b02661
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Ligand-Promoted Pd(II)-Catalyzed Functionalization of Unactivated C(sp3)–H Bond: Regio- and Stereoselective Synthesis of Arylated Rimantadine Derivatives

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DOI: 10.1021/acscatal.5b02483
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Switching of “Rollover Pathway” in Rhodium(III)-Catalyzed C–H Activation of Chelating Molecules

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DOI: 10.1021/acscatal.5b02540
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Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C–H Activation and Ring Opening

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DOI: 10.1021/acscatal.5b02414
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Palladium–Silver Cooperativity in an Aryl Amination Reaction through C–H Functionalization

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DOI: 10.1021/acscatal.5b02639
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Rh(III)-Catalyzed [4 + 2] Annulation of Indoles with Diazo Compounds: Access to Pyrimido[1,6-a]indole-1(2H)-ones

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DOI: 10.1021/acs.orglett.5b03231
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Ir(III)-Catalyzed Synthesis of Isoquinoline N-Oxides from Aryloxime and α-Diazocarbonyl Compounds

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DOI: 10.1021/acs.orglett.5b03462
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Rh(I)-Catalyzed Insertion of Allenes into C–C Bonds of Benzocyclobutenols

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DOI: 10.1021/acs.orglett.5b03518
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Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C–H Bond Activation

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DOI: 10.1021/acs.orglett.5b03474
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Access to 3-Acyl-(2H)-indazoles via Rh(III)-Catalyzed C–H Addition and Cyclization of Azobenzenes with α-Keto Aldehydes

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DOI: 10.1021/acs.orglett.5b03368
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Sunday, January 10, 2016

Formal Gold- and Rhodium-Catalyzed Regiodivergent C–H Alkynylation of 2-Pyridones

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DOI: 10.1021/acs.joc.5b02410
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C–H-Activated Direct Arylation of Strong Benzothiadiazole and Quinoxaline-Based Electron Acceptors

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DOI: 10.1021/acs.joc.5b02551
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