The Negishi Catalysis: Full Study of the Complications in the Transmetalation Step and Consequences for the Coupling Products

DOI: 10.1021/acs.organomet.6b00660

DFT Study on the Mechanism of Tandem Oxidative Acetoxylation/Ortho C–H Activation/Carbocyclization Catalyzed by Pd(OAc)2

DOI: 10.1021/acs.organomet.6b00503

Base-Promoted, Aerobic, and Regioselective Carbon–Hydrogen Bond Activation of Thiophene with Group 9 Metalloporphyrins

DOI: 10.1021/acs.organomet.6b00490

Palladium-Catalyzed Carbonylative Cyclization of Amines via γ-C(sp3)–H Activation: Late-Stage Diversification of Amino Acids and Peptides

DOI: 10.1021/acscatal.6b01987

Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles

DOI: 10.1021/acscatal.6b01452

Rhodium(II)-Catalyzed Undirected and Selective C(sp2)–H Amination en Route to Benzoxazolones

DOI: 10.1021/acscatal.6b02237

Synthesis of Cyclopentadienols by Rhodium-Catalyzed C–H Activation of 8-Formylquinolines and [2+2+1] Carbocyclization with Alkynes

DOI: 10.1021/acscatal.6b01936

Nonclassical Routes for Amide Bond Formation

Carbaporphyrinoid Systems

A Simple and Versatile Reactor for Photochemistry

DOI: 10.1021/acs.oprd.6b00257

Catalytic C–H Arylation of Aliphatic Aldehydes Enabled by a Transient Ligand

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

DOI: 10.1021/jacs.6b08397

Branch-Selective Hydroarylation: Iodoarene–Olefin Cross-Coupling

Isolated Organometallic Nickel(III) and Nickel(IV) Complexes Relevant to Carbon–Carbon Bond Formation Reactions

Palladium(II)-Catalyzed Regioselective syn-Hydroarylation of Disubstituted Alkynes Using a Removable Directing Group

DOI: 10.1021/jacs.6b08818

Ion Pair-Directed Regiocontrol in Transition-Metal Catalysis: A Meta-Selective C–H Borylation of Aromatic Quaternary Ammonium Salts

DOI: 10.1021/jacs.6b08164

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

DOI: 10.1021/jacs.6b04789

Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes

DOI: 10.1021/jacs.6b07844

The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination

DOI: 10.1021/acs.accounts.6b00247

Enantioselective Cyclopropanation of a Wide Variety of Olefins Catalyzed by Ru(II)–Pheox Complexes

Anti-Markovnikov Oxidation of β-Alkyl Styrenes with H2O as the Terminal Oxidant

DOI: 10.1021/jacs.6b07411

Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity

DOI: 10.1021/jacs.6b08075

Conversion of Simple Cyclohexanones into Catechols

DOI: 10.1021/jacs.6b07269

Photochemical Synthesis of Carbazoles Using an [Fe(phen)3](NTf2)2/O2 Catalyst System: Catalysis toward Sustainability

DOI: 10.1021/acs.orglett.6b02456

Functionalization of Azacalixaromatics by Cu(II)-Catalyzed Oxidative Cross-Coupling Reaction between the Arene C–H Bond and Boronic Acids

DOI: 10.1021/acs.orglett.6b02530

Metal-Free Visible-Light-Mediated Oxidative Cross-Coupling of Thiols with P(O)H Compounds Using Air as the Oxidant

DOI: 10.1021/acs.orglett.6b02563

Palladium-Catalyzed Cascade Arene/Alkyne Annulation: Synthesis of Fluorene-Benzoxazine Derivatives

DOI: 10.1021/acs.orglett.6b02224

Nickel-Catalyzed Site-Selective C–H Bond Difluoroalkylation of 8-Aminoquinolines on the C5-Position

DOI: 10.1021/acs.orglett.6b02166

Transition-Metal-Free Cross-Coupling of Aryl Halides with Arylstannanes

DOI: 10.1021/acs.joc.6b01648

Iridium(III)-Catalyzed Regioselective C7-Amination of N-Pivaloylindoles with Sulfonoazides

DOI: 10.1021/acs.joc.6b01856

Controlled Fluoroalkylation Reactions by Visible-Light Photoredox Catalysis

DOI: 10.1021/acs.accounts.6b00248

A Comparative Reactivity Survey of Some Prominent Bisphosphine Nickel(II) Precatalysts in C–N Cross-Coupling

DOI: 10.1021/acs.organomet.6b00650

Palladium(0)-Catalyzed Asymmetric C–H Alkenylation for Efficient Synthesis of Planar Chiral Ferrocenes

DOI: 10.1021/acs.organomet.6b00569

Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing Various Triarylphosphines and Their Use for Arylation of Sterically Congested Aromatic C–H Bonds

DOI: 10.1021/acs.organomet.6b00540

Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2

DOI: 10.1021/acscatal.6b02124

Visible Light Photocatalytic Aerobic Oxygenation of Indoles and pH as a Chemoselective Switch

DOI: 10.1021/acscatal.6b01969

Palladium-Catalyzed Carbonylative Cyclization of Amines via γ-C(sp3)–H Activation: Late-Stage Diversification of Amino Acids and Peptides

DOI: 10.1021/acscatal.6b01987

Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles

DOI: 10.1021/acscatal.6b01452

Palladium-Catalyzed Intramolecular Hydroaminocarbonylation to Lactams: Additive-Free Protocol Initiated by Palladium Hydride

DOI: 10.1021/acscatal.6b01939

Nickel-Catalyzed Decarbonylative Borylation and Silylation of Esters

DOI: 10.1021/acscatal.6b01956