Scalable and Selective Preparation of 3,3′,5,5′-Tetramethyl-2,2′-biphenol

DOI: 10.1021/acs.oprd.6b00356

An Organometalllic NiIV Complex That Participates in Competing Transmetalation and C(sp2)–O Bond-Forming Reductive Elimination Reactions

DOI: 10.1021/acs.organomet.6b00810

Recent Advances in Transition-Metal-Catalyzed Synthetic Transformations of Organosilicon Reagents

DOI: 10.1021/acscatal.6b02374

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

DOI: 10.1021/acscatal.6b02518

Asymmetric Transformations under Iridium/Chiral Diene Catalysis

DOI: 10.1021/acscatal.6b02495

Access to Isoquinolin-1(2 H)-ones and Pyridones by Cobalt-Catalyzed Oxidative Annulation of Amides with Allenes

DOI: 10.1002/cctc.201601190

Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki–Miyaura Cross Coupling

DOI: 10.1021/acscentsci.6b00283

Controllable Rh(III)-Catalyzed Annulation between Salicylaldehydes and Diazo Compounds: Divergent Synthesis of Chromones and Benzofurans

DOI: 10.1021/acs.orglett.6b03355

Cobalt(III)-Catalyzed Regio- and Stereoselective α-Fluoroalkenylation of Arenes with gem-Difluorostyrenes

DOI: 10.1021/acs.orglett.6b03203

Ru-Catalyzed One-Pot Diannulation of Heteroaryls: Direct Access to π-Conjugated Polycyclic Amides

DOI: 10.1021/acs.orglett.6b03314

Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C–H Activation

DOI: 10.1021/acs.orglett.6b03244

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

Rh(III)-Catalyzed Aryl and Alkenyl C–H Bond Addition to Diverse Nitroalkenes

DOI: 10.1021/acscatal.6b03217

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

DOI: 10.1021/acscatal.6b02181

Iron/Zinc-Co-catalyzed Directed Arylation and Alkenylation of C(sp3)–H Bonds with Organoborates

DOI: 10.1021/acscatal.6b02927

Recycling in Asymmetric Catalysis

DOI: 10.1021/acs.accounts.6b00396

Cobalt-Catalyzed C(sp2)–H Borylation with an Air-Stable, Readily Prepared Terpyridine Cobalt(II) Bis(acetate) Precatalyst

DOI: 10.1021/acs.organomet.6b00630

Nickel-Catalyzed Oxidative Coupling of Unactivated C(sp3)–H Bonds in Aliphatic Amides with Terminal Alkynes

DOI: 10.1021/acs.organomet.6b00529

Synthesis of o-Alkenylated 2-Arylbenzoxazoles via Rh-Catalyzed Oxidative Olefination of 2-Arylbenzoxazoles: Scope Investigation, Structural Features, and Mechanism Studies

DOI: 10.1021/acs.joc.6b01836

Rhodium-Catalyzed Oxidative Synthesis of Quinoline-Fused Sydnones via 2-fold C–H Bond Activation

DOI: 10.1021/acs.joc.6b02356

A Regioselective Metal-Free Construction of 3-Aroyl Coumarins by Csp2-H Functionalization

DOI: 10.1021/acs.joc.6b02051

Palladium-Catalyzed Arylation of Ketones and Acetonitrile with Ortho Alkylation of Aryl Rings: De Novo Synthesis of Tetralines and Benzocycloheptenes

DOI: 10.1021/acs.orglett.6b03130

Direct ortho-Arylation of Pyridinecarboxylic Acids: Overcoming the Deactivating Effect of sp2-Nitrogen

DOI: 10.1021/acs.orglett.6b03085

Synthesis of Cycloalkyl Substituted 7-Azaindoles via Photoredox Nickel Dual Catalytic Cross-Coupling in Batch and Continuous Flow

DOI: 10.1021/acs.orglett.6b03223

Visible-Light Photo-Arbuzov Reaction of Aryl Bromides and Trialkyl Phosphites Yielding Aryl Phosphonates

DOI: 10.1021/acscatal.6b02591

Highly Efficient Synthesis of Alkylboronate Esters via Cu(II)-Catalyzed Borylation of Unactivated Alkyl Bromides and Chlorides in Air

DOI: 10.1021/acscatal.6b02918

Late Stage Azidation of Complex Molecules

DOI: 10.1021/acscentsci.6b00214

The Negishi Catalysis: Full Study of the Complications in the Transmetalation Step and Consequences for the Coupling Products

DOI: 10.1021/acs.organomet.6b00660

DFT Study on the Mechanism of Tandem Oxidative Acetoxylation/Ortho C–H Activation/Carbocyclization Catalyzed by Pd(OAc)2

DOI: 10.1021/acs.organomet.6b00503

Base-Promoted, Aerobic, and Regioselective Carbon–Hydrogen Bond Activation of Thiophene with Group 9 Metalloporphyrins

DOI: 10.1021/acs.organomet.6b00490

Palladium-Catalyzed Carbonylative Cyclization of Amines via γ-C(sp3)–H Activation: Late-Stage Diversification of Amino Acids and Peptides

DOI: 10.1021/acscatal.6b01987

Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles

DOI: 10.1021/acscatal.6b01452

Rhodium(II)-Catalyzed Undirected and Selective C(sp2)–H Amination en Route to Benzoxazolones

DOI: 10.1021/acscatal.6b02237

Synthesis of Cyclopentadienols by Rhodium-Catalyzed C–H Activation of 8-Formylquinolines and [2+2+1] Carbocyclization with Alkynes

DOI: 10.1021/acscatal.6b01936

Nonclassical Routes for Amide Bond Formation

Carbaporphyrinoid Systems

A Simple and Versatile Reactor for Photochemistry

DOI: 10.1021/acs.oprd.6b00257

Catalytic C–H Arylation of Aliphatic Aldehydes Enabled by a Transient Ligand

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

DOI: 10.1021/jacs.6b08397

Branch-Selective Hydroarylation: Iodoarene–Olefin Cross-Coupling

Isolated Organometallic Nickel(III) and Nickel(IV) Complexes Relevant to Carbon–Carbon Bond Formation Reactions

Palladium(II)-Catalyzed Regioselective syn-Hydroarylation of Disubstituted Alkynes Using a Removable Directing Group

DOI: 10.1021/jacs.6b08818

Ion Pair-Directed Regiocontrol in Transition-Metal Catalysis: A Meta-Selective C–H Borylation of Aromatic Quaternary Ammonium Salts

DOI: 10.1021/jacs.6b08164

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

DOI: 10.1021/jacs.6b04789

Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes

DOI: 10.1021/jacs.6b07844

The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination

DOI: 10.1021/acs.accounts.6b00247

Enantioselective Cyclopropanation of a Wide Variety of Olefins Catalyzed by Ru(II)–Pheox Complexes

Anti-Markovnikov Oxidation of β-Alkyl Styrenes with H2O as the Terminal Oxidant

DOI: 10.1021/jacs.6b07411

Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity

DOI: 10.1021/jacs.6b08075

Conversion of Simple Cyclohexanones into Catechols

DOI: 10.1021/jacs.6b07269