Raji Chem World

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Wednesday, December 13, 2017

Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment


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Catalytic Organic Reactions in Water toward Sustainable Society


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Redox-Tag Processes: Intramolecular Electron Transfer and Its Broad Relationship to Redox Reactions in General


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Sunday, November 26, 2017

Catalyst-controlled oligomerization for the collective synthesis of polypyrroloindoline natural products


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Recent advances in catalytic C−H borylation reactions


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Thursday, November 23, 2017

Group 6 Dihapto-Coordinate Dearomatization Agents for Organic Synthesis


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Mechanism of Rhodium-Catalyzed C–H Functionalization: Advances in Theoretical Investigation


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Achieving Molecular Complexity via Stereoselective Multiple Domino Reactions Promoted by a Secondary Amine Organocatalyst


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Experimental–Computational Synergy for Selective Pd(II)-Catalyzed C–H Activation of Aryl and Alkyl Groups

DOI: 10.1021/acs.accounts.7b00440

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Speciation in iron epoxidation catalysis: A perspective on the discovery and role of non-heme iron(III)-hydroperoxo species in iron-catalyzed oxidation reactions


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Piano-stool N-heterocyclic carbene iron complexes: Synthesis, reactivity and catalytic applications


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Monday, November 20, 2017

Toward Green Acylation of (Hetero)arenes: Palladium-Catalyzed Carbonylation of Olefins to Ketones

DOI: 10.1021/acscentsci.7b00368

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Building Diversity in ortho-Substituted s-Aryltetrazines By Tuning N-Directed Palladium C–H Halogenation: Unsymmetrical Polyhalogenated and Biphenyl s-Aryltetrazines

DOI: 10.1021/acscatal.7b03186

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Ruthenium-Catalyzed C–H Benzoxylation of tert-Benzamides with Aromatic Acids by Weak Coordination

DOI: 10.1021/acs.joc.7b02495

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Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines


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Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N-(2-Haloaryl)acrylamides

DOI: 10.1021/acs.organomet.7b00702

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Rhodium Complexes of 2,6-Bis(dialkylphosphinomethyl)pyridines: Improved C–H Activation, Expanded Reaction Scope, and Catalytic Direct Arylation

DOI: 10.1021/acs.organomet.7b00532

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Copper-Mediated C–X Functionalization of Aryl Halides

DOI: 10.1021/acs.oprd.7b00285

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OMS-2/H2O2/Dimethyl Carbonate: An Environmentally-Friendly Heterogeneous Catalytic System for the Oxidative Synthesis of Benzoxazoles at Room Temperature

DOI: 10.1021/acs.oprd.7b00315

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Copper-Catalyzed Dehydrogenative Formal [4 + 2] and [3 + 2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes

DOI: 10.1021/acs.orglett.7b03194

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Mechanochemical Ruthenium-Catalyzed Hydroarylations of Alkynes under Ball-Milling Conditions

DOI: 10.1021/acs.orglett.7b02973

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Non-Metal-Catalyzed Heterodehydrocoupling of Phosphines and Hydrosilanes: Mechanistic Studies of B(C6F5)3-Mediated Formation of P–Si Bonds

DOI: 10.1021/jacs.7b09175

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Electronic Effects on Room-Temperature, Gas-Phase C–H Bond Activations by Cluster Oxides and Metal Carbides: The Methane Challenge

DOI: 10.1021/jacs.7b10139

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Experimental and Theoretical Studies on Iron-Promoted Oxidative Annulation of Arylglyoxal with Alkyne: Unusual Addition and Migration on the Aryl Ring

DOI: 10.1021/jacs.7b05981

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Selective ortho C–H Activation of Pyridines Directed by Lewis Acidic Boron of PBP Pincer Iridium Complexes

10.1021/jacs.7b10570

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Diastereodivergent Asymmetric Carboamination/Annulation of Cyclopropenes with Aminoalkenes by Chiral Lanthanum Catalysts

10.1021/jacs.7b10786

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Sunday, November 5, 2017

Mechanism of Nakamura’s Bisphosphine-Iron-Catalyzed Asymmetric C(sp2)–C(sp3) Cross-Coupling Reaction: The Role of Spin in Controlling Arylation Pathways


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Cation Radical Accelerated Nucleophilic Aromatic Substitution via Organic Photoredox Catalysis


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Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation


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Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via β-C(sp3)–H Activation


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Rhodium/Copper Cocatalyzed Highly trans-Selective 1,2-Diheteroarylation of Alkynes with Azoles via C–H Addition/Oxidative Cross-Coupling: A Combined Experimental and Theoretical Study

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Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis


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Chemoselective Intermolecular Cross-Enolate-Type Coupling of Amides

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Coupling N–H Deprotonation, C–H Activation, and Oxidation: Metal-Free C(sp3)–H Aminations with Unprotected Anilinesications)


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Tuesday, October 31, 2017

Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis


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Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization


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Monday, October 23, 2017

Ligand-Enabled γ-C(sp3)–H Cross-Coupling of Nosyl-Protected Amines with Aryl- and Alkylboron Reagents


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Use of Electrochemistry in the Synthesis of Heterocyclic Structures


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Three-Component Catalytic Carboxygenation of Activated Alkenes Enabled by Bimetallic Rh(III)/Cu(II) Catalysis


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Rhodium-Catalyzed Direct Ortho C–H Arylation Using Ketone as Directing Group with Boron Reagent


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Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides


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Cobalt-Catalyzed Oxidative Cyclization of Benzamides with Maleimides: Synthesis of Isoindolone Spirosuccinimides

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Iridium/Bipyridine-Catalyzed ortho-Selective C–H Borylation of Phenol and Aniline Derivatives


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Rhodium-Catalyzed [4 + 3] Annulations of Sulfoximines with α,β-Unsaturated Ketones Leading to 1,2-Benzothiazepine 1-Oxides


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Transition-Metal-Free C–CN/C–H Cross-Coupling: Effect of Cyano Group


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Total Synthesis and Anti-inflammatory Evaluation of Penchinone A and Its Structural Analogues


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Palladium-Catalyzed Direct C(sp2)–H ortho-Arylation of Anilides Using 2-Aminophenylpyrazole as the Directing Group


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Sunday, October 22, 2017

A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System


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Factors Controlling the Reactivity and Chemoselectivity of Resonance Destabilized Amides in Ni-Catalyzed Decarbonylative and Nondecarbonylative Suzuki-Miyaura Coupling


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Through-Space Activation Can Override Substituent Effects in Electrophilic Aromatic Substitution


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