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Sunday, September 22, 2019

Harnessing Secondary Coordination Sphere Interactions That Enable the Selective Amidation of Benzylic C–H Bonds

10.1021/jacs.9b07795
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Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex

10.1021/jacs.9b08185
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Para-Selective, Iridium-Catalyzed C–H Borylations of Sulfated Phenols, Benzyl Alcohols, and Anilines Directed by Ion-Pair Electrostatic Interactions

10.1021/jacs.9b08464
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Catalytic Cleavage of C(sp2)–C(sp2) Bonds with Rh-Carbynoids

10.1021/jacs.9b08632
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Hemilabile Benzyl Ether Enables γ-C(sp3)–H Carbonylation and Olefination of Alcohols

10.1021/jacs.9b08238
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Para-Selective C–H Borylation of Common Arene Building Blocks Enabled by Ion-Pairing with a Bulky Countercation

10.1021/jacs.9b07267
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Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides

10.1038/s41596-019-0209-8
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Fulfilling four roles

10.1002/anie.201908627
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Mechanistic Study on the Decarboxylative sp3 C–N Cross-Coupling between Alkyl Carboxylic Acids and Nitrogen Nucleophiles via Dual Copper and Photoredox Catalysis

10.1021/acs.inorgchem.9b01477
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Generation of Heteroatom Stereocenters by Enantioselective C–H Functionalization

10.1021/acscatal.9b03194
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3-Acetoxyquinuclidine as Catalyst in Electron Donor–Acceptor Complex-Mediated Reactions Triggered by Visible Light

10.1021/acscatal.9b01039
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RhCl3·3H2O-Catalyzed Ligand-Enabled Highly Regioselective Thiolation of Acrylic Acids

10.1021/acscatal.9b02982
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Recent Advances in Pyridinium Salts as Radical Reservoirs in Organic Synthesis

10.1021/acscatal.9b03084
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Copper-Catalyzed Carbon–Silicon Bond Formation

10.1021/acscatal.9b02762
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Bifunctional Copper-Based Photocatalyst for Reductive Pinacol-Type Couplings

10.1021/acscatal.9b01718
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Alkene Synthesis by Photocatalytic Chemoenzymatically Compatible Dehydrodecarboxylation of Carboxylic Acids and Biomass

10.1021/acscatal.9b02951
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Metallalkenyl, Metallacyclopropene, or Metallallylcarbenoid? Ru-Catalyzed Annulation between Benzoic Acid and Alkyne

10.1021/acscatal.9b02952
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Nickel/Cobalt-Catalyzed C(sp3)–C(sp3) Cross-Coupling of Alkyl Halides with Alkyl Tosylates

10.1021/acscatal.9b03352
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Conjugated Ynones in Organic Synthesis

10.1021/acs.chemrev.9b00277
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