Friday, February 3, 2012

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

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Cobalt catalysts for the coupling of CO2 and epoxides to provide polycarbonates and cyclic carbonates

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This comprehensive  tutorial review  focuses on well-defined cobalt complexes that serve as homogeneous catalysts for the production of ...

Green chemistry oriented organic synthesis in water

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The use of water as solvent features many benefits such as improving reactivities and selectivities, simplifying the workup procedures,...
Thursday, February 2, 2012

Oxidative Prins and Prins/Friedel–Crafts cyclizations for the stereoselective synthesis of dioxabicycles and hexahydro-1H-benzo[f]isochromenes via the benzylic C–H activation

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1-Benzyl ethers of ( E )- and ( Z )-hex-3-en-1,6-diols and hept-3-en-1,7-diols undergo a smooth oxidative cyclization with DDQ in the pr...

The Triple Role of Fluoride Ions in Palladium-Catalyzed Suzuki–Miyaura Reactions: Unprecedented Transmetalation from [ArPdFL2] Complexes

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Direct Titanium-Mediated Conversion of Ketones into Enamides with Ammonia and Acetic Anhydride

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Tuesday, January 31, 2012

Tuning the Regioselectivity of Palladium-Catalyzed Direct Arylation of Azoles by Metal Coordination

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Cationic Ruthenium(II) Catalysts for Oxidative C–H/N–H Bond Functionalizations of Anilines with Removable Directing Group: Synthesis of Indoles in Water

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Synthesis of Indolo [1,2-a]Quinoxalines via a Pd-Catalyzed Regioselective C–H Olefination/Cyclization Sequence

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Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

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Tandem Rh(III)-Catalyzed Oxidative Acylation of Secondary Benzamides with Aldehydes and Intramolecular Cyclization: The Direct Synthesis of 3-Hydroxyisoindolin-1-ones

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Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

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Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages

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Iron-Catalyzed Regio- and Stereoselective Chlorosulfonylation of Terminal Alkynes with Aromatic Sulfonyl Chlorides

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Terminal alkynes react with aromatic sulfonyl chlorides in the presence of an iron(II) catalyst and a phosphine ligand to give (E)-β-ch...

Rhodium-Catalyzed Xanthone Formation from 2-Aryloxybenzaldehydes via Cross-Dehydrogenative Coupling (CDC)

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