Raji Chem World

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Monday, April 30, 2012

Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites

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Rhodium-catalyzed oxidative C2-acylation of indoles with aryl and alkyl aldehydes

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Friday, April 27, 2012

High-valent organometallic copper and palladium in catalysis

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Nature   484 ,   177–185   (12 April 2012)

A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes

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Nature Chemistry   4 ,   405–409   (2012)

Selective synthesis of 3-hydroxy acids from Meldrum's acids using SmI2-H2O : Nature Protocols

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Nature Protocols 7, 970–977 (2012) 

Heck-Type Cross-Dehydrogenative Coupling Reactions of Indolizines at the 3-Position with Electron-Deficient Alkenes through Palladium-Catalyzed C[BOND]H Activation

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Thursday, April 26, 2012

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

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Iodine(III)-Mediated Intermolecular Allylic Amination under Metal-Free Conditions

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Rh2(II)-Catalyzed Intramolecular Aliphatic C–H Bond Amination Reactions Using Aryl Azides as the N-Atom Source

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Highly Selective Intramolecular Carbene Insertion into Primary C–H Bond of α-Diazoacetamides Mediated by a (p-Cymene)ruthenium(II) Carboxylate Complex

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Wednesday, April 25, 2012

Generation of 4-polyfluoroaryl pyrrolo[1,2-a]quinolines via C–H bond activation

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Heterogeneously catalyzed selective aerobic oxidative cross-coupling of terminal alkynes and amides with simple copper(ii) hydroxide

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Cu(i)-catalyzed annulation for the synthesis of substituted naphthalenes using o-bromobenzaldehydes and β-ketoesters as substrates

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Tuesday, April 24, 2012

Palladium-Catalyzed Direct C[BOND]H Arylation of Enamides with Simple Arenes

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Synthesis of Fluorene Derivatives through Rhodium-Catalyzed Dehydrogenative Cyclization

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