An efficient and clean method to construct C![[BOND]](https://lh3.googleusercontent.com/blogger_img_proxy/AEn0k_vzmfNw_7CpOM48iv41QDRMa8EyIwnBFS4LlJq3pKkRdAla3vPVx_wizW66_hcqytuaz9eyMmUDxZW9tdFbSMjgxskxiFQU14fbm9jdxrelli6MoYWjmVIBG6QMe5O0wzcxf8yQZVbeET50Lw=s0-d)
C bonds has been developed via the acylation reaction of acetanilides with benzylic alcohols using tert-butyl hydroperoxide (TBHP) as oxidant catalyzed by palladium acetate in the presence of triflic acid (TfOH). The acylation reactions exhibit excellent reactivities, and up to 95% yield of the corresponding aryl ketone could be obtained under the optimal conditions.
C bonds has been developed via the acylation reaction of acetanilides with benzylic alcohols using tert-butyl hydroperoxide (TBHP) as oxidant catalyzed by palladium acetate in the presence of triflic acid (TfOH). The acylation reactions exhibit excellent reactivities, and up to 95% yield of the corresponding aryl ketone could be obtained under the optimal conditions.
DOI: 10.1002/adsc.201100417
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