An efficient and clean method to construct C![[BOND]](https://lh3.googleusercontent.com/blogger_img_proxy/AEn0k_srR-RyKJoWTCxozKPo_3czSgR1zuincOisipZO08eN8XaPpJYm3AvqC89PZHg41QwU6xtVC3ypVwWg6akAPT0zcYpyls0IWKSaaIrIY4xTca8FCQ8qPvmbzDzLFmlHLdryzd_WNP_poL-fgg=s0-d)
C bonds has been developed via the acylation reaction of acetanilides with benzylic alcohols using tert-butyl hydroperoxide (TBHP) as oxidant catalyzed by palladium acetate in the presence of triflic acid (TfOH). The acylation reactions exhibit excellent reactivities, and up to 95% yield of the corresponding aryl ketone could be obtained under the optimal conditions.
C bonds has been developed via the acylation reaction of acetanilides with benzylic alcohols using tert-butyl hydroperoxide (TBHP) as oxidant catalyzed by palladium acetate in the presence of triflic acid (TfOH). The acylation reactions exhibit excellent reactivities, and up to 95% yield of the corresponding aryl ketone could be obtained under the optimal conditions.
DOI: 10.1002/adsc.201100417
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