Rhodium-catalyzed oxidative coupling through C–H activation and annulation directed by phosphonamide and phosphinamide groups

Rhodium-catalyzed oxidative coupling through C–H activation and annulation directed by phosphonamide and phosphinamide groups - Chemical Communications (RSC Publishing)

Rhodium(iii)-catalyzed vinylic sp2 C–H bond functionalization: efficient synthesis of pyrido[1,2-α]benzimidazoles and imidazo[1,2-α]pyridines

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

Chem. Sci., 2013,4, 3912-3916

Pd(ii)-catalyzed alkylation of unactivated C(sp3)–H bonds: efficient synthesis of optically active unnatural α-amino acids

Chem. Sci., 2013,4, 3906-3911

Cu(i)-catalyzed intramolecular oxidative C–H amination of 2-aminoacetophenones: a convenient route toward isatins

Chem. Commun., 2013,49, 8540-8542

A convenient synthesis of quinolizinium salts through Rh(iii) or Ru(ii)-catalyzed C–H bond activation of 2-alkenylpyridines

Chem. Commun., 2013,49, 8528-8530

Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl C[BOND]H Activation

DOI: 10.1002/chem.201300829

Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C[BOND]H Bond Activation

DOI: 10.1002/chem.201301987

Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes

New Strategies for Transition-Metal-Catalyzed C-P Bond Formation

Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol

Palladium-catalyzed selective decarboxylative coupling reaction versus direct C―H arylation for arylation of heteroaromatics

Selectivity based on heteroatom:

DOI: 10.1002/aoc.3037

Nickel-Catalyzed Chemo- and Stereoselective Alkenylative Cyclization of 1,6-Enynes with Alkenyl Boronic Acids

Twofold Unsymmetrical C[BOND]H Functionalization of PyrDipSi-Substituted Arenes: A General Method for the Synthesis of Substituted meta-Halophenols

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyOx) ligand

Chiral Ligand Synthesis:

Beilstein J. Org. Chem. 2013, 9, 1637–1642.

Gold-catalyzed intermolecular coupling of sulfonylacetylene with allyl ethers: [3,3]- and [1,3]-rearrangements

Synthesis of 1,4 diene using gold catalyst:

Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process

Iron can do this:

Beilstein J. Org. Chem. 2013, 9, 1718–1723

Aerobic C–H Acetoxylation of 8-Methylquinoline in PdII–Pyridinecarboxylic Acid Systems: Some Structure–Reactivity Relationships

Rh(III)-Catalyzed Tandem C–H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles

Cu-Catalyzed Cross-Dehydrogenative Coupling Reactions of (Benzo)thiazoles with Cyclic Ethers

Carboxylate Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

A Versatile Approach to Ullmann C–N Couplings at Room Temperature: New Families of Nucleophiles and Electrophiles for Photoinduced, Copper-Catalyzed Processes

Bioconjugation by Native Chemical Tagging of C–H Bonds

Pt-Catalyzed C–C Activation Induced by C–H Activation

Palladium-Catalyzed Allylic C–H Fluorination

One-pot direct C–H arylation of arenes in water catalysed by RuCl3·nH2O–NaOAc in the presence of Zn

Synthesis of heterocyclic-fused benzofurans via C–H functionalization of flavones and coumarins

Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl C[BOND]H Activation

Palladium/Copper-Catalyzed Oxidative C[BOND]H Alkenylation/N-Dealkylative Carbonylation of Tertiary Anilines

Palladium/Copper-Catalyzed Oxidative C[BOND]H Alkenylation/N-Dealkylative Carbonylation of Tertiary Anilines

Regioselective Hydroarylations and Parallel Kinetic Resolution of Vince Lactam

Palladium-Catalyzed Hydrobenzylation of ortho-Tolyl Alkynyl Ethers by Benzylic C[BOND]H Activation: Remarkable Alkynoxy-Directing Effect

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Allenes by the [3+2] Annulation of Aryl Ketimines

C–H Functionalization of Cyclopropanes: A Practical Approach Employing a Picolinamide Auxiliary

ortho-Acetoxylation of Phosphonic and Phosphoric Monoacids via Pd(II) Catalysis

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

Rh-catalyzed sulfonic acid group directed ortho C–H olefination of arenes

l-Proline–TBAB-catalyzed phosgene free synthesis of methyl carbamates from amines and dimethyl carbonate

Atropodiastereoselective C[BOND]H Olefination of Biphenyl p-Tolyl Sulfoxides with Acrylates

Metal-Free Oxidative Coupling: Xanthone Formation via Direct Annulation of 2-Aryloxybenzaldehyde using Tetrabutylammonium Bromide as a Promoter in Aqueous Medium

Silver-Catalyzed Decarboxylative Acylarylation of Acrylamides with α-Oxocarboxylic Acids in Aqueous Media

Switchable Synthesis of 3-Cyanoindoles and 3-Amidylindoles via a Palladium-Catalyzed Reaction of N,N-Dimethyl-2-alkynylaniline with Isocyanide

8-Aminoquinoline: A Powerful Directing Group in Metal-Catalyzed Direct Functionalization of C[BOND]H Bonds

DOI: 10.1002/anie.201303556

Palladium-Catalyzed C[BOND]H ortho Arylation of Benzoic Acids with Diaryliodonium Salts in Water

α-Arylation, α-Arylative Esterification, or Acylation: A Stoichiometry-Dependent Trichotomy in the Pd-Catalyzed Cross-Coupling between Aldehydes and Aryl Bromides

A convenient synthesis of quinolizinium salts through Rh(iii) or Ru(ii)-catalyzed C–H bond activation of 2-alkenylpyridines

DOI: 10.1039/C3CC45004J

Stereoselective Synthesis of β-Alkylated α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated Methylene C(sp3)–H Bonds with Primary Alkyl Halides