Transition-Metal-Free Enantioselective Reactions of Organo­magnesium Reagents Mediated by Chiral Ligands

DOI: 10.1055/s-0037-1610135

Transition-Metal-Free Cross-Coupling of Aryl Halides with Arylstannanes

DOI: 10.1021/acs.joc.6b01648

One Photocatalyst, n Activation Modes Strategy for Cascade Catalysis: Emulating Coumarin Biosynthesis with (−)-Riboflavin

DOI: 10.1021/jacs.5b12081

An Unprecedented Formal [5 + 2] Cycloaddition of Nitrones with o-Carboryne via Tandem [3 + 2] Cycloaddition/Oxygen Migration/Aromatization Sequence

DOI: 10.1021/jacs.5b09074

Transition Metal-Free ipso-Functionalization of Arylboronic Acids and Derivatives

DOI: 10.1002/adsc.201400305

Solvent-Free and Catalysts-Free Chemistry: A Benign Pathway to Sustainability

A simple, efficient, regioselective and one-pot preparation of N-hydroxy- and N-O-protected hydroxyindoles via cycloaddition of nitrosoarenes with alkynes. Synthetic scope, applications and novel by-products

Recent advances in transition-metal-free direct C–C and C–heteroatom bond forming reactions

DOI: 10.1039/C3RA40813B

Cycloaddition-based Formal C–H Alkynylation of Isoindoles Leading to the Synthesis of Air-stable Fluorescent 1,3-Dialkynylisoindoles

Metal-free, highly efficient organocatalytic amination of benzylic C–H bonds

nBu4NI-catalyzed unexpected amide bond formation between aldehydes and aromatic tertiary amines

Synthesis of 3,5-Disubstituted Pyrazoles via Cope-Type Hydroamination of 1,3-Dialkynes

Microwave promoted catalyst-free benzylic C–H functionalization of methyl quinoline and Michael addition to beta-nitro styrene

Elusive Metal-Free Primary Amination of Arylboronic Acids: Synthetic Studies and Mechanism by Density Functional Theory

Metal-free n-Bu4NI-catalyzed direct synthesis of amides from alcohols and N,N-disubstituted formamides

Transition-Metal-Free Oxyarylation of Alkenes with Aryl Diazonium Salts and TEMPONa - Journal of the American Chemical Society (ACS Publications)

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

Catalyst-Free N-Arylation Using Unactivated Fluorobenzenes

Direct Amidation of Alcohols with N-Substituted Formamides under Transition-Metal-Free Conditions

TBHP/I2-promoted oxidative coupling of acetophenones with amines at room temperature under metal-free and solvent-free conditions for the synthesis of α-ketoamides

A novel and efficient TBHP/I₂-promoted oxidative coupling reaction of acetophenones with amines for the synthesis of α-ketoamides has been developed. The reactions proceeded smoothly at room temperature under metal-free and solvent-free conditions and generated the corresponding products in good yields.