Oxime directed aromatic C−H bond activation and oxidative coupling to alkenes is reported using a cationic Rh(III) catalyst. Significantly, the method can be used to oxidatively couple unactivated, aliphatic alkenes.
Org. Lett. 2011, 540.
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Friday, June 24, 2011
Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation
Oxime directed aromatic C−H bond activation and oxidative coupling to alkenes is reported using a cationic Rh(III) catalyst. Significantly, the method can be used to oxidatively couple unactivated, aliphatic alkenes.
Org. Lett. 2011, 540.
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