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Monday, January 28, 2013

Direct Access to Acylated Azobenzenes via Pd-Catalyzed C–H Functionalization and Further Transformation into an Indazole Backbone

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Synthesis of Quinolones by Nickel-Catalyzed Cycloaddition via Elimination of Nitrile

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Synthesis of 3-Acylindoles by Palladium-Catalyzed Acylation of Free (N–H) Indoles with Nitriles

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Mechanistic Investigation of Palladium-Catalyzed Allylic C–H Activation

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CuI-Catalyzed Cross-Coupling of N-Tosylhydrazones with Terminal Alkynes: Synthesis of 1,3-Disubstituted Allenes

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Pd(II)-Catalyzed Aerobic Oxidative Intramolecular Hydroamination and C-H Functionalization of N-Alkynyl Anilines for the Synthesis of Indole Derivatives

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Wednesday, January 23, 2013

Direct Lactonization of 2-Arylacetic Acids through Pd(II)-Catalyzed C–H Activation/C–O Formation

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Ruthenium-Catalyzed C–H Oxygenation on Aryl Weinreb Amides

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Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins

A Cationic High-Valent Cp*CoIII Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed C[BOND]H Bond Activation

Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

Graphical abstract: Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

A Unique Palladium Catalyst for Efficient and Selective Alkoxycarbonylation of Olefins with Formates

Thursday, January 17, 2013

Palladium-Acetate Catalyst for Regioselective Direct Arylation at C2 of 3-Furanyl or 3-Thiophenyl Acrylates with Inhibition of Heck Type Reaction

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Tetrahedron - Pd(II)-Catalyzed Intramolecular Aminopalladation/Direct C-H Arylation Under Aerobic Conditions: Synthesis of Pyrrolo[1,2-a]indoles

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Pd(OAc)2 catalyzed C-H activation of 1,3,4-oxadiazoles and their direct oxidative coupling with benzothiazoles and aryl boronic acids using Cu(OAc)2 as an oxidant

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Carboxylate-assisted ruthenium(II)-catalyzed C–H arylations of 5-aryl tetrazoles: Step-economical access to Valsartan

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Pd-catalyzed decarboxylative ortho-acylation of O-methyl oximes with phenylglyoxylic acids

Graphical abstract: Pd-catalyzed decarboxylative ortho-acylation of O-methyl oximes with phenylglyoxylic acids

Monday, January 14, 2013

Palladium-Catalyzed Decarboxylative Suzuki and Heck Couplings of Azaindole-2-carboxylic Acids: Synthesis of 2-Aryl/Alkenyl-1-phenylsulfonyl-1 H-pyrrolo-[2,3 b]pyridines

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Mechanistic Investigations and Substrate Scope Evaluation of Ruthenium-Catalyzed Direct sp3 Arylation of Benzylic Positions Directed by 3-Substituted Pyridines

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Nucleophilic Addition of Benzimidazoles to Alkynyl Bromides/Palladium-Catalyzed Intramolecular C–H Vinylation: Synthesis of Benzo[4,5]imidazo[2,1-a]isoquinolines

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Palladium-Catalyzed Saegusa–Ito Oxidation: Synthesis of α,β-Unsaturated Carbonyl Compounds from Trimethylsilyl Enol Ethers

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A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

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