Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy

DOI: 10.1021/acs.chemrev.0c00278

 

3-Acetoxyquinuclidine as Catalyst in Electron Donor–Acceptor Complex-Mediated Reactions Triggered by Visible Light

10.1021/acscatal.9b01039

Recent Advances in Pyridinium Salts as Radical Reservoirs in Organic Synthesis

10.1021/acscatal.9b03084

Organocobalt Complexes as Sources of Carbon-Centered Radicals for Organic and Polymer Chemistries

10.1021/acs.chemrev.8b00715

Recent Advances in the Synthesis of β‐Functionalized Ketones by Radical‐Mediated 1,2‐Rearrangement of Allylic Alcohols

DOI: 10.1002/chem.201800004

Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation

Coupling N–H Deprotonation, C–H Activation, and Oxidation: Metal-Free C(sp3)–H Aminations with Unprotected Anilinesications)

Electrocatalytic Minisci Acylation Reaction of N-Heteroarenes Mediated by NH4I

Trifluoromethylation of Alkyl Radicals in Aqueous Solution

DOI: 10.1021/jacs.7b06044

Metal-Free Tandem Oxidative Coupling of Primary Alcohols with Azoles for the Synthesis of Hemiaminal Ethers

DOI: 10.1021/acs.joc.5b02516

Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes

DOI: 10.1039/C5CC09730D

Transition-Metal Hydride Radical Cations

DOI: 10.1021/acs.chemrev.5b00532

Sulfate Radical Anion (SO4•–) Mediated C(sp3)–H Nitrogenation/Oxygenation in N-Aryl Benzylic Amines Expanded the Scope for the Synthesis of Benzamidine/Oxazine Heterocycles

DOI: 10.1021/acs.joc.5b01872

Copper-Catalyzed Oxidative C–H Amination of Tetrahydrofuran with Indole/Carbazole Derivatives

DOI: 10.1021/acs.joc.5b01990

Recent Advances on Palladium Radical Involved Reactions

Oxidative Povarov Reaction via sp3 C–H Oxidation of N-Benzylanilines Induced by Catalytic Radical Cation Salt: Synthesis of 2,4-Diarylquinoline Derivatives

DOI: 10.1021/acs.orglett.5b00244

Aerobic Oxidation of PdII to PdIV by Active Radical Reactants: Direct C–H Nitration and Acylation of Arenes via Oxygenation Process with Molecular Oxygen

DOI: 10.1021/cs502126n

Copper(i)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3 C–H functionalisation

DOI: 10.1039/C4OB01962H

Copper catalyzed room temperature lactonization of aromatic C–H bond: a novel and efficient approach for the synthesis of dibenzopyranones

DOI: 10.1039/C4RA13665A

Recent Advances of Transition-Metal Catalyzed Radical Oxidative Cross-Couplings

DOI: 10.1021/ar5002044