Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes

DOI: 10.1021/acs.chemrev.6b00567

Facile synthesis of dibranched conjugated dienes via palladium-catalyzed oxidative coupling of N-tosylhydrazones

A Straightforward Approach to 3, 3'-Bipyrroles by Oxidative Homocoupling of 1, 2, 5-Trisubstituted Pyrroles

Dehydrogenative alkenylation of uracils via palladium-catalyzed regioselective C–H activation

Pd-catalyzed oxidative C–H/C–H cross-coupling of pyridines with heteroarenes

Palladium-Catalyzed Intermolecular Dehydrogenative Aminohalogenation of Alkenes under Molecular Oxygen: An Approach to Brominated Enamines

Copper-Mediated C[BOND]H/C[BOND]H Biaryl Coupling of Benzoic Acid Derivatives and 1,3-Azoles

Synthesis of imidazo and benzimidazo[2,1-a]isoquinolines by rhodium-catalyzed intramolecular double C–H bond activation

Insight into the palladium catalyzed oxidative arylation of benzofuran: Heteropoly acid oxidants evoke a Pd(II)/Pd(IV) mechanism

Synthesis of Functionalized Spiroindolines via Palladium-Catalyzed Methine C–H Arylation

Palladium-Catalyzed Oxidative Cross-Coupling between Heterocycles and Terminal Alkynes with Low Catalyst Loading

Mild Copper-Mediated Direct Oxidative Cross-Coupling of 1,3,4-Oxadiazoles with Polyfluoroarenes by Using Dioxygen as Oxidant

Rhodium- and Iridium-Catalyzed Dehydrogenative Cyclization through Double C–H Bond Cleavages To Produce Fluorene Derivatives

Palladium-Catalyzed Coupling of Polyfluorinated Arenes with Heteroarenes via C–F/C–H Activation

Pd(OAc)2 catalyzed C–H activation of 1,3,4-oxadiazoles and their direct oxidative coupling with benzothiazoles and aryl boronic acids using Cu(OAc)2 as an oxidant

Pd(OAc)2 catalyzed C-H activation of 1,3,4-oxadiazoles and their direct oxidative coupling with benzothiazoles and aryl boronic acids using Cu(OAc)2 as an oxidant

Elements of Regiocontrol in the Direct Heteroarylation of Indoles/Pyrroles: Synthesis of Bi- and Fused Polycyclic Heteroarenes by Twofold or Tandem Fourfold C[BOND]H Activation

Synthesis of substituted quinolines by iron-catalyzed oxidative coupling reactions

Copper(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Azoles

Pd-catalyzed double C–H bond activation of diaryl ketones for the synthesis of fluorenones

An efficient synthesis of fluorenones from diaryl ketones by Pd-catalyzed oxidative cyclization is described. A possible mechanism involving a carbonyl group assisted ortho-C–H activation and cyclometalation followed by a second C–H activation to form a six-membered palladacycle and reductive elimination is proposed.