Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites

Rhodium-catalyzed oxidative C2-acylation of indoles with aryl and alkyl aldehydes

High-valent organometallic copper and palladium in catalysis

Nature

 

484,

 

177–185

 

(12 April 2012)

A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes

Nature Chemistry

 

4,

 

405–409

 

(2012)

Selective synthesis of 3-hydroxy acids from Meldrum's acids using SmI2-H2O : Nature Protocols

Nature Protocols 7, 970–977 (2012) 

Heck-Type Cross-Dehydrogenative Coupling Reactions of Indolizines at the 3-Position with Electron-Deficient Alkenes through Palladium-Catalyzed C[BOND]H Activation

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

Iodine(III)-Mediated Intermolecular Allylic Amination under Metal-Free Conditions

Rh2(II)-Catalyzed Intramolecular Aliphatic C–H Bond Amination Reactions Using Aryl Azides as the N-Atom Source

Highly Selective Intramolecular Carbene Insertion into Primary C–H Bond of α-Diazoacetamides Mediated by a (p-Cymene)ruthenium(II) Carboxylate Complex

Generation of 4-polyfluoroaryl pyrrolo[1,2-a]quinolines via C–H bond activation

Heterogeneously catalyzed selective aerobic oxidative cross-coupling of terminal alkynes and amides with simple copper(ii) hydroxide

Cu(i)-catalyzed annulation for the synthesis of substituted naphthalenes using o-bromobenzaldehydes and β-ketoesters as substrates

Palladium-Catalyzed Direct C[BOND]H Arylation of Enamides with Simple Arenes

Synthesis of Fluorene Derivatives through Rhodium-Catalyzed Dehydrogenative Cyclization

Switch of Selectivity in the Synthesis of α-Methylene-γ-Lactones: Palladium-Catalyzed Intermolecular Carboesterification of Alkenes with Alkynes

Enantioselective β-Arylation of Ketones Enabled by Lithiation/Borylation/1,4-Addition Sequence Under Flow Conditions

Mild Rhodium(III)-Catalyzed C[BOND]H Activation and Intermolecular Annulation with Allenes - Wang - 2012 - Angewandte Chemie International Edition - Wiley Online Library

Metal-Catalyzed One-Pot Synthesis of Tetrazines Directly from Aliphatic Nitriles and Hydrazine

Aerobic Amide Bond Formation with N-hydroxysuccinimide

Palladium-catalyzed monoselective C–H borylation of acetanilides under acidic conditions

Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation

Wiley: Innovative Catalysis in Organic Synthesis: Oxidation, Hydrogenation, and C-X Bond Forming Reactions

Synthesis of 4H-cyclopenta[c]furans via cooperative PdCl2–FeCl2 catalyzed cascade cyclization reaction involving a novel acyl rearrangement process

Sulfoximines: A Reusable Directing Group for Chemo- and Regioselective ortho C[BOND]H Oxidation of Arenes

DOI: 10.1002/chem.201200092

Iron-Promoted Tandem Reaction of Anilines with Styrene Oxides via C–C Cleavage for the Synthesis of Quinolines - Organic Letters (ACS Publications)

Rhodium-Catalyzed Synthesis of Branched Amines by Direct Addition of Benzamides to Imines

Well-Defined Ruthenium(II) Carboxylate as Catalyst for Direct C–H/C–O Bond Arylations with Phenols in Water

Synthesis of [60]Fullerene-Fused Sultones via Sulfonic Acid Group-Directed C–H Bond Activation

Lewis Acid-Catalyzed, Copper(II)-Mediated Synthesis of Heteroaryl Thioethers under Base-Free Conditions

Dehydrative C–H Alkylation and Alkenylation of Phenols with Alcohols: Expedient Synthesis for Substituted Phenols and Benzofurans

DOI: 10.1021/ja302710v

Gold(I)-Catalyzed Stereoconvergent, Intermolecular Enantioselective Hydroamination of Allenes

A General Pd-Catalyzed Decarboxylative Cross-Coupling Reaction between Aryl Carboxylic Acids: Synthesis of Biaryl Compounds

Palladium(II)-Catalyzed Intramolecular Diamination of Alkynes under Aerobic Oxidative Conditions: Catalytic Turnover of an Iodide Ion - Yao - 2012 - Angewandte Chemie International Edition - Wiley Online Library

Nickel-Catalyzed Regio- and Stereoselective Reductive Coupling between Methylenecyclopropanes, Aldehydes, and Triethylborane with Retention of the Cyclopropane Ring

DOI: 10.1002/chem.201200271

CDC Reactions of N-Aryl Tetrahydroisoquinolines Using Catalytic Amounts of DDQ: C[BOND]H Activation under Aerobic Conditions

Nickel-catalyzed C–H direct amination of benzoxazoles with secondary amines

Synthesis of carbazolones and 3-acetylindoles via oxidative C–N bond formation through PIFA-mediated annulation of 2-aryl enaminones

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Transition metal-catalysed intermolecular reaction of allenes with oxygen nucleophiles: a perspective

Ion-paired chiral ligands for asymmetric palladium catalysis

Nature Chemistry (2012) doi:10.1038/nchem.1311

Copper-Catalyzed Di- and Trifluoromethylation of α,β-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations

Catalytic Enantioselective Alkene Aminohalogenation/Cyclization Involving Atom Transfer

Efficient Copper(II)-Catalyzed Transamidation of Non-Activated Primary Carboxamides and Ureas with Amines

Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd-Catalyzed Intramolecular Asymmetric α-Arylation of α-Branched Aldehydes

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

High-valent organometallic copper and palladium in catalysis

Nature 484, 177–185 (12 April 2012)

Metal-free TEMPO-catalyzed oxidative C–C bond formation from Csp3–H bonds using molecular oxygen as the oxidant

A bifunctional catalyst for carbon dioxide fixation: cooperative double activation of epoxides for the synthesis of cyclic carbonates

Room-Temperature Copper-Catalyzed Oxidation of Electron-Deficient Arenes and Heteroarenes Using Air

Palladium-Catalyzed Alkylation of 1,4-Dienes by C[BOND]H Activation