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Nature Chemistry

Monday, December 29, 2014

Cobalt(III)-Catalyzed Synthesis of Indazoles and Furans by C–H Bond Functionalization/Addition/Cyclization Cascades

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DOI: 10.1021/ja5116452

Copper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of Heterocycles

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DOI: 10.1021/cr500410y

Palladium-Catalyzed ortho-Sulfonylation of 2-Aryloxypyridines and Subsequent Formation of ortho-Sulfonylated Phenols

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DOI: 10.1021/jo5026095

Synthesis of Benzofused Five-Ring Sultams via Rh-Catalyzed C–H Olefination Directed by an N-Ac-Substituted Sulfonamide Group

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DOI: 10.1021/jo502224d

Silver-Catalyzed C(sp2)–H Functionalization/C–O Cyclization Reaction at Room Temperature

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DOI: 10.1021/jo5024238

RhIII-Catalyzed Redox-Neutral C–H Activation of Pyrazolones: An Economical Approach for the Synthesis of N-Substituted Indoles

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DOI: 10.1021/ol503404p

Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide

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DOI: 10.1021/ol5034018

Monday, December 22, 2014

Pd-Catalyzed Monoselective ortho-C–H Alkylation of N-Quinolyl Benzamides: Evidence for Stereoretentive Coupling of Secondary Alkyl Iodides

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DOI: 10.1021/ja511557h

Palladium-Catalyzed ortho-Selective C–H Fluorination of Oxalyl Amide-Protected Benzylamines

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DOI: 10.1021/jo502365b

Rhodium(III)-Catalyzed Hydrazine-Directed C–H Activation for Indole Synthesis: Mechanism and Role of Internal Oxidant Probed by DFT Studies

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DOI: 10.1021/om501130c

Computational Mechanistic Study of Palladium(II)-Catalyzed Carboxyalkynylation of an Olefin Using an Iodine(III) Oxidant Reagent

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DOI: 10.1021/om5011758

Pd-Catalyzed Dehydrogenative Aryl–Aryl Bond Formation via Double C(sp2)–H Bond Activation: Efficient Synthesis of [3,4]-Fused Oxindoles

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DOI: 10.1021/ol503442n

Palladium-Catalyzed Synthesis of Six-Membered Benzofuzed Phosphacycles via Carbon–Phosphorus Bond Cleavage

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Silver-Catalyzed C–H Trifluoromethylation of Arenes Using Trifluoroacetic Acid as the Trifluoromethylating Reagent

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DOI: 10.1021/ol503189j

Rh(III)-Catalyzed Selenylation of Arenes with Selenenyl Chlorides/Diselenides via C–H Activation

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DOI: 10.1021/ol503231

Cobalt-Catalyzed Enantioselective Directed C–H Alkylation of Indole with Styrenes

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DOI: 10.1021/ol503119z

Monday, December 8, 2014

Tandem Catalysis: Rh(III)-Catalyzed C–H Allylation/Pd(II)-Catalyzed N-Allylation Toward the Synthesis of Vinyl-Substituted N-Heterocycles

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DOI: 10.1021/cs501601c

Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl Acetates: Synthesis of 3-Substituted Isocoumarins

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DOI: 10.1021/jo502231y

Mild Rhodium(III)-Catalyzed C–H Allylation with 4-Vinyl-1,3-dioxolan-2-ones: Direct and Stereoselective Synthesis of (E)-Allylic Alcohols

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DOI: 10.1021/ol503229c

Facile Synthesis of 6-Acylated Pyrido[2,1-a]isoindoles from 2-Arylpyridines and γ-Substituted tert-Propargyl Alcohols via Rhodium-Catalyzed C–H Bond Activation and β-Carbon Elimination

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DOI: 10.1021/ol503157k

Modern Carbon–Fluorine Bond Forming Reactions for Aryl Fluoride Synthesis

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DOI: 10.1021/cr500366b

Cobalt–Bisoxazoline-Catalyzed Asymmetric Kumada Cross-Coupling of Racemic α-Bromo Esters with Aryl Grignard Reagents

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DOI: 10.1021/ja5109084

Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8Ï€ Insertion

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DOI: 10.1021/ja5105206

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