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Nature Chemistry

Monday, January 26, 2015

Palladium-Catalyzed Carbonylation of Indoles for Synthesis of Indol-3-yl Aryl Ketones

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DOI: 10.1021/cs5019106

Electrophilic Halogenation–Reductive Elimination Chemistry of Organopalladium and -Platinum Complexes

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DOI: 10.1021/ar500325x

Rhodium-Catalyzed Borylation of Aryl 2-Pyridyl Ethers through Cleavage of the Carbon–Oxygen Bond: Borylative Removal of the Directing Group

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Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

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DOI: 10.1021/ja511796h

Mild Rh(III)-Catalyzed C7-Allylation of Indolines with Allylic Carbonates

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DOI: 10.1021/jo502733q

Palladium-Catalyzed Regioselective Benzylation–Annulation of Pyridine N-Oxides with Toluene Derivatives via Multiple C–H Bond Activations: Benzylation versus Arylation

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DOI: 10.1021/ol503238a

Assembly of Indoline-2-carboxylate-Embodied Dipeptides via Pd-Catalyzed C(sp2)–H Bond Direct Functionalization

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DOI: 10.1021/ol503514t

Cobalt-Catalyzed C–H Cyanation of (Hetero)arenes and 6-Arylpurines with N-Cyanosuccinimide as a New Cyanating Agent

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DOI: 10.1021/ol503680d

Thursday, January 22, 2015

Copper(i)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3 C–H functionalisation

Graphical abstract: Copper(i)-promoted cycloalkylation–peroxidation of unactivated alkenes via sp3 C–H functionalisation
DOI: 10.1039/C4OB01962H

Cu-catalyzed arylation of the amino group in the indazole ring: regioselective synthesis of pyrazolo-carbazoles

Graphical abstract: Cu-catalyzed arylation of the amino group in the indazole ring: regioselective synthesis of pyrazolo-carbazoles
DOI: 10.1039/C4OB02044H

Ligand-Promoted ortho-C[BOND]H Amination with Pd Catalysts

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DOI: 10.1002/anie.201408651

Orchestrated Triple C[BOND]H Activation Reactions Using Two Directing Groups: Rapid Assembly of Complex Pyrazoles

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DOI: 10.1002/anie.201410462

General Method for the Synthesis of Salicylic Acids from Phenols through Palladium-Catalyzed Silanol-Directed C[BOND]H Carboxylation

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DOI: 10.1002/anie.201410375

RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed C[BOND]C Bond Cleavages

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DOI: 10.1002/chem.20140571

Iron-Catalyzed Trifluoromethylation of Enamide

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DOI: 10.1002/chem.201406333

Tuesday, January 20, 2015

Decarboxylative acylation of arenes with mandelic acid derivatives via palladium-catalyzed oxidative sp2 C–H activation

Graphical abstract: Decarboxylative acylation of arenes with mandelic acid derivatives via palladium-catalyzed oxidative sp2 C–H activation
DOI: 10.1039/C4RA14107E

Pd-Catalyzed Direct C–H Bond Sulfonylation of Azobenzenes with Arylsulfonyl Chlorides

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DOI: 10.1021/jo502451k

Iridium(III)-Catalyzed C-7 Selective C–H Alkynylation of Indolines at Room Temperature

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DOI: 10.1021/jo502596k

Rhodium(III)-Catalyzed Oxidative Alkenylation of 1,3-Dithiane-Protected Arenecarbaldehydes via Regioselective C–H Bond Cleavage

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DOI: 10.1021/ol503722r

Synthesis of Benzofuro[3,2-b]pyridines via Palladium-Catalyzed Dual C–H Activation of 3-Phenoxypyridine 1-Oxides

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DOI: 10.1021/ol5033464

Pd-Catalyzed Intramolecular C–N Bond Cleavage, 1,4-Migration, sp3 C–H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand

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DOI: 10.1021/ja512212x

Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins

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DOI: 10.1021/ja512306a

Palladium(II)-Catalyzed Intramolecular Tandem Aminoalkylation via Divergent C(sp3)–H Functionalization

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DOI: 10.1021/ja5102739

Pd(II)-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation

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DOI: 10.1021/ja512029x

Monday, January 12, 2015

The Azomethine Ylide Route to Amine C–H Functionalization: Redox-Versions of Classic Reactions and a Pathway to New Transformations

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DOI: 10.1021/ar5003768

Robust Ruthenium(II)-Catalyzed C–H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers

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DOI: 10.1021/op500330g

Iron-Catalyzed Directed C2-Alkylation and Alkenylation of Indole with Vinylarenes and Alkynes

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DOI: 10.1021/ol503395g

Palladium-Catalyzed Oxidative Carbonylation of Aromatic C–H Bonds of N-Alkylanilines with CO and Alcohols for the Synthesis of o-Aminobenzoates

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DOI: 10.1021/jo502581p

Cobalt(III)-Catalyzed C–H Amidation of Arenes using Acetoxycarbamates as Convenient Amino Sources under Mild Conditions

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DOI: 10.1021/cs501860b

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