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Nature Chemistry

Monday, September 30, 2013

Rhodium(III)-Catalyzed Intermolecular N-Chelator-Directed Aromatic C–H Amidation with Amides

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Metal-Free Oxidative Spirocyclization of Hydroxymethylacrylamide with 1,3-Dicarbonyl Compounds: A New Route to Spirooxindoles

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Palladium-Catalyzed C-2 Selective Arylation of Quinolines

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Ruthenium-Catalyzed C–H Activation/Cyclization for the Synthesis of Phosphaisocoumarins

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Cp*IrIII-Catalyzed Oxidative Coupling of Benzoic Acids with Alkynes

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Cu-Catalyzed Esterification Reaction via Aerobic Oxygenation and C–C Bond Cleavage: An Approach to α-Ketoesters

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Mechanism and Enantioselectivity in Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β-Substituted Cyclic Enones: Insights from Computation and Experiment

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Metal-Free Synthesis of 3,3-Disubstituted Oxindoles via 1,2-Alkylarylation of Activated Alkenes with Alcohols

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Iron-catalyzed alkenylation of cyclic ethers via decarboxylative sp3(C)-sp2(C) coupling

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Tuesday, September 24, 2013

Gold(I)-Catalyzed Protodecarboxylation of (Hetero)Aromatic Carboxylic Acids

Copper-Catalyzed Trifluoromethylation–Cyclization of Enynes: Highly Regioselective Construction of Trifluoromethylated Carbocycles and Heterocycles

A Highly Efficient Palladium-Catalyzed Decarboxylative ortho-Acylation of Azobenzenes with α-Oxocarboxylic Acids: Direct Access to Acylated Azo Compounds

Palladium-Catalyzed Direct Synthesis of Phosphole Derivatives from Triarylphosphines through Cleavage of Carbon–Hydrogen and Carbon–Phosphorus Bonds

Rhodium(III)-Catalyzed Azidation and Nitration of Arenes by C[BOND]H Activation

Iron-Catalyzed Carbonylation-Arylation of N-Arylacrylamides for Synthesis of Oxindole Derivatives

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Copper-catalyzed oxidative coupling of carboxylic acids with formamides for the synthesis of α, β-unsaturated amides

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Monday, September 23, 2013

Kinetic Analysis of Aqueous-Phase Pd-Catalyzed, Cu-Free Direct Arylation of Terminal Alkynes Using a Hydrophilic Ligand

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Computational Perspective on Pd-Catalyzed C–C Cross-Coupling Reaction Mechanisms

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Controlling the Ambiphilic Nature of σ-Arylpalladium Intermediates in Intramolecular Cyclization Reactions

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Understanding the Reactivity of Pd0/PR3-Catalyzed Intermolecular C(sp3)–H Bond Arylation

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Rh(III)-Catalyzed C–H Activation and Double Directing Group Strategy for the Regioselective Synthesis of Naphthyridinones

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Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp2)–N Bond Formation of Conjugated Tosyl Amides

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Mechanistic Origin of Chemo- and Regioselectivity of Nickel-Catalyzed [3 + 2 + 2] Cyclization Reaction

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γ-Carbonyl Quinones: Radical Strategy for the Synthesis of Evelynin and Its Analogues by C–H Activation of Quinones Using Cyclopropanols

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Pd(0)-Catalyzed 1,1-Diarylation of Ethylene and Allylic Carbonates

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Pd-Catalyzed Direct Arylation of Nitro(pentafluorosulfanyl)benzenes with Aryl Bromides

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Rhodium Catalyzed Cyanation of Chelation Assisted C–H Bonds

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Palladium-Catalyzed β-Arylation of Silyl Ketene Acetals and Application to the Synthesis of Benzo-Fused δ-Lactones

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Palladium-Catalyzed Direct ortho Alkoxylation of Aromatic Azo Compounds with Alcohols

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Scope and Limitations of Auxiliary-Assisted, Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C–H Bonds

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Selective Direct Heterocoupling of Alkenes Catalyzed by in Situ Generated Ruthenium Complexes

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