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Nature Chemistry

Monday, July 29, 2013

Palladium(II)-Catalyzed Direct Carboxylation of Alkenyl C–H Bonds with CO2

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Povarov-Reductive Amination Cascade to Access 6-Aminoquinolines and Anthrazolines

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Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1-Oxides - Organic Letters (ACS Publications)

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DOI: 10.1021/ol401775t

Three-Bond Breaking of Cyclic Anhydrides: Easy Access to Polyfunctionalized Naphthalenes and Phenanthrenes

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Rh(III)-Catalyzed Halogenation of Vinylic C–H Bonds: Rapid and General Access to Z-Halo Acrylamides

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Ruthenium-Catalyzed Regioselective C–H Alkenylation Directed by a Free Amino Group

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DOI: 10.1021/ol401779h

Monday, July 15, 2013

Computational Perspective on Pd-Catalyzed C–C Cross-Coupling Reaction Mechanisms

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DOI: 10.1021/ar400080r

Rhodium(III)-Catalyzed C–H Activation and Amidation of Arenes Using N-Arenesulfonated Imides as Amidating Reagents

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Cu(OTf)2-Catalyzed Selective Arene C–H Bond Hydroxylation and Nitration with KNO2 as an Ambident O- and N-Nucleophile via a Cu(II)–Cu(III)–Cu(I) Mechanism

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DOI: 10.1021/ol401453f

Aerobic Dehydrogenative Heck Reaction of Ferrocene with a Pd(OAc)2/4,5-Diazafluoren-9-one Catalyst

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DOI: 10.1021/om400410u

Regioselective Cyclometalation of Planar Chiral Pyridine and Oxazoline Derivatives: peri- versus ortho-C–H Functionalization

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DOI: 10.1021/om4004175

Factors Controlling the Reactivity of Heteroarenes in Direct Arylation with Arylpalladium Acetate Complexes

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DOI: 10.1021/om400636r

Heterogeneous CeO2-catalyzed selective synthesis of cyclic carbamates from CO2 and aminoalcohols in acetonitrile solvent

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Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group

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DOI: 10.1021/ja4056239

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

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DOI: 10.1021/ja405950c

Pd(II)-Catalyzed C–H Iodination Using Molecular I2 as the Sole Oxidant

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DOI: 10.1021/ja4055492

Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids

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DOI: 10.1021/ja405949a

Rhodium-Catalyzed Directed C–H Cyanation of Arenes with N-Cyano-N-phenyl-p-toluenesulfonamide

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DOI: 10.1021/ja405742y

Rhodium-Catalyzed C3-Selective Alkenylation of Substituted Thiophene-2-carboxylic Acids and Related Compounds

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DOI: 10.1021/jo4011969

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