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Nature Chemistry

Monday, January 25, 2016

Palladium(II)-Catalyzed, Heteroatom-Directed, Regioselective C–H Nitration of Anilines Using Pyrimidine as a Removable Directing Group

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DOI: 10.1021/acs.orglett.5b03493

Cross-Coupling Hydrogen Evolution by Visible Light Photocatalysis Toward C(sp2)–P Formation: Metal-Free C–H Functionalization of Thiazole Derivatives with Diarylphosphine Oxides

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DOI: 10.1021/acs.orglett.5b03497

N-Iodosuccinimide-Promoted Hofmann–Löffler Reactions of Sulfonimides under Visible Light

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DOI: 10.1021/acs.orglett.5b03476

Copper-Catalyzed Regioselective C–H Sulfonylation of 8-Aminoquinolines

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DOI: 10.1021/acs.joc.5b02509

Pd/C-Catalyzed Aminocarbonylation of Aryl Iodides via Oxidative C–N Bond Activation of Tertiary Amines to Tertiary Amides

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DOI: 10.1021/acs.joc.5b02385

Regioselective Electrophilic Fluorination of Rationally Designed Imidazole Derivatives

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DOI: 10.1021/acs.joc.5b02592

Metal-Catalyzed Directed Regio- and Enantioselective Ring-Opening of Epoxides

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DOI: 10.1021/acs.accounts.5b00428

Monday, January 18, 2016

Access to Different Isomeric Dibenzoxazepinones through Copper-Catalyzed C–H Etherification and C–N Bond Construction with Controllable Smiles Rearrangement

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DOI: 10.1021/acs.orglett.5b03378

Ruthenium Catalyzed Intramolecular C–S Coupling Reactions: Synthetic Scope and Mechanistic Insight

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DOI: 10.1021/acs.orglett.5b03185

Palladium-Catalyzed Regioselective Arylation of Pyrazolo[1,5-a]pyridines via C–H Activation and Synthetic Applications on P38 Kinase Inhibitors

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DOI: 10.1021/acs.organomet.5b00988

C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis

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Donor–Acceptor Fluorophores for Visible-Light-Promoted Organic Synthesis: Photoredox/Ni Dual Catalytic C(sp3)–C(sp2) Cross-Coupling

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DOI: 10.1021/acscatal.5b02204

Asymmetric Conjugate Addition of Organoboron Reagents to Common Enones Using Copper Catalysts

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DOI: 10.1021/jacs.5b11441

One Photocatalyst, n Activation Modes Strategy for Cascade Catalysis: Emulating Coumarin Biosynthesis with (−)-Riboflavin

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DOI: 10.1021/jacs.5b12081

Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C–H Bonds

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DOI: 10.1021/jacs.5b12153

Metal-Free CH–CH-Type Cross-Coupling of Arenes and Alkynes Directed by a Multifunctional Sulfoxide Group

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DOI: 10.1021/jacs.5b12579

Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

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DOI: 10.1021/jacs.5b11311

Friday, January 15, 2016

Synthesis of N-Containing Heterocyclic Compounds Using Visible-light Photoredox Catalysis

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DOI: 10.1002/tcr.201500228

Cobalt(iii) catalyzed C-8 selective C–H and C–O coupling of quinoline N-oxide with internal alkynes via C–H activation and oxygen atom transfer

Graphical abstract: Cobalt(iii) catalyzed C-8 selective C–H and C–O coupling of quinoline N-oxide with internal alkynes via C–H activation and oxygen atom transfer
DOI: 10.1039/C5CC08736H

Copper mediated decarboxylative direct C–H arylation of heteroarenes with benzoic acids

Graphical abstract: Copper mediated decarboxylative direct C–H arylation of heteroarenes with benzoic acids
DOI: 10.1039/C5CC08367B

Photocatalyst-free hypervalent iodine reagent catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids driven by visible-light irradiation

Graphical abstract: Photocatalyst-free hypervalent iodine reagent catalyzed decarboxylative acylarylation of acrylamides with α-oxocarboxylic acids driven by visible-light irradiation
DOI: 10.1039/C5CC08253F

Iron(ii) triflate/N-heterocyclic carbene-catalysed cross-coupling of arylmagnesiums with aryl chlorides and tosylates

Graphical abstract: Iron(ii) triflate/N-heterocyclic carbene-catalysed cross-coupling of arylmagnesiums with aryl chlorides and tosylates

Visible light-promoted C–H functionalization of ethers and electron-deficient arenes

Graphical abstract: Visible light-promoted C–H functionalization of ethers and electron-deficient arenes
DOI: 10.1039/C5CC08817H

Chemo- and Regioselective Ethynylation of Tryptophan-Containing Peptides and Proteins

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DOI: 10.1002/chem.201504462

Direct Synthesis of Protoberberine Alkaloids by Rh-Catalyzed C[BOND]H Bond Activation as the Key Step

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DOI: 10.1002/chem.201504378

Copper-Catalyzed 8-Amido Chelation-Induced Remote C[BOND]H Amination of Quinolines

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DOI: 10.1002/chem.201504207

Merging Visible-Light Photocatalysis and Palladium Catalysis for C[BOND]H Acylation of Azo- and Azoxybenzenes with α-Keto Acids

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DOI: 10.1002/chem.201504530

Enantioselective Access to Spirocyclic Sultams by Chiral Cpx–Rhodium(III)-Catalyzed Annulations

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DOI: 10.1002/chem.201504998

Identifying a Highly Active Copper Catalyst for KA2 Reaction of Aromatic Ketones

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DOI: 10.1002/chem.201504823

One-Pot Sequential Propargylation/Cycloisomerization: A Facile [4+2]-Benzannulation Approach to Carbazoles

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DOI: 10.1002/chem.201503496

Monday, January 11, 2016

Nickel N-Heterocyclic Carbene-Catalyzed C–Heteroatom Bond Formation, Reduction, and Oxidation: Reactions and Mechanistic Aspects

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DOI: 10.1021/acscatal.5b02021

Mechanism of the Visible Light-Mediated Gold-Catalyzed Oxyarylation Reaction of Alkenes

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DOI: 10.1021/acscatal.5b01971

Mechanism and Origins of Ligand-Controlled Linear Versus Branched Selectivity of Iridium-Catalyzed Hydroarylation of Alkenes

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DOI: 10.1021/acscatal.5b02201

Factors Controlling Stability and Reactivity of Dimeric Pd(II) Complexes in C–H Functionalization Catalysis

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DOI: 10.1021/acscatal.5b02447

Oxazolinyl-Assisted C–H Amidation by Cobalt(III) Catalysis

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DOI: 10.1021/acscatal.5b02661

Ligand-Promoted Pd(II)-Catalyzed Functionalization of Unactivated C(sp3)–H Bond: Regio- and Stereoselective Synthesis of Arylated Rimantadine Derivatives

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DOI: 10.1021/acscatal.5b02483

Switching of “Rollover Pathway” in Rhodium(III)-Catalyzed C–H Activation of Chelating Molecules

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DOI: 10.1021/acscatal.5b02540

Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C–H Activation and Ring Opening

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DOI: 10.1021/acscatal.5b02414

Palladium–Silver Cooperativity in an Aryl Amination Reaction through C–H Functionalization

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DOI: 10.1021/acscatal.5b02639

Rh(III)-Catalyzed [4 + 2] Annulation of Indoles with Diazo Compounds: Access to Pyrimido[1,6-a]indole-1(2H)-ones

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DOI: 10.1021/acs.orglett.5b03231

Ir(III)-Catalyzed Synthesis of Isoquinoline N-Oxides from Aryloxime and α-Diazocarbonyl Compounds

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DOI: 10.1021/acs.orglett.5b03462

Rh(I)-Catalyzed Insertion of Allenes into C–C Bonds of Benzocyclobutenols

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DOI: 10.1021/acs.orglett.5b03518

Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C–H Bond Activation

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DOI: 10.1021/acs.orglett.5b03474

Access to 3-Acyl-(2H)-indazoles via Rh(III)-Catalyzed C–H Addition and Cyclization of Azobenzenes with α-Keto Aldehydes

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DOI: 10.1021/acs.orglett.5b03368

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