Catalyst-controlled oligomerization for the collective synthesis of polypyrroloindoline natural products

Recent advances in catalytic C−H borylation reactions

Group 6 Dihapto-Coordinate Dearomatization Agents for Organic Synthesis

Mechanism of Rhodium-Catalyzed C–H Functionalization: Advances in Theoretical Investigation

Achieving Molecular Complexity via Stereoselective Multiple Domino Reactions Promoted by a Secondary Amine Organocatalyst

Experimental–Computational Synergy for Selective Pd(II)-Catalyzed C–H Activation of Aryl and Alkyl Groups

DOI: 10.1021/acs.accounts.7b00440

Speciation in iron epoxidation catalysis: A perspective on the discovery and role of non-heme iron(III)-hydroperoxo species in iron-catalyzed oxidation reactions

Piano-stool N-heterocyclic carbene iron complexes: Synthesis, reactivity and catalytic applications

Toward Green Acylation of (Hetero)arenes: Palladium-Catalyzed Carbonylation of Olefins to Ketones

DOI: 10.1021/acscentsci.7b00368

Building Diversity in ortho-Substituted s-Aryltetrazines By Tuning N-Directed Palladium C–H Halogenation: Unsymmetrical Polyhalogenated and Biphenyl s-Aryltetrazines

DOI: 10.1021/acscatal.7b03186

Ruthenium-Catalyzed C–H Benzoxylation of tert-Benzamides with Aromatic Acids by Weak Coordination

DOI: 10.1021/acs.joc.7b02495

Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines

Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N-(2-Haloaryl)acrylamides

DOI: 10.1021/acs.organomet.7b00702

Rhodium Complexes of 2,6-Bis(dialkylphosphinomethyl)pyridines: Improved C–H Activation, Expanded Reaction Scope, and Catalytic Direct Arylation

DOI: 10.1021/acs.organomet.7b00532

Copper-Mediated C–X Functionalization of Aryl Halides

DOI: 10.1021/acs.oprd.7b00285

OMS-2/H2O2/Dimethyl Carbonate: An Environmentally-Friendly Heterogeneous Catalytic System for the Oxidative Synthesis of Benzoxazoles at Room Temperature

DOI: 10.1021/acs.oprd.7b00315

Copper-Catalyzed Dehydrogenative Formal [4 + 2] and [3 + 2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes

DOI: 10.1021/acs.orglett.7b03194

Mechanochemical Ruthenium-Catalyzed Hydroarylations of Alkynes under Ball-Milling Conditions

DOI: 10.1021/acs.orglett.7b02973

Non-Metal-Catalyzed Heterodehydrocoupling of Phosphines and Hydrosilanes: Mechanistic Studies of B(C6F5)3-Mediated Formation of P–Si Bonds

DOI: 10.1021/jacs.7b09175

Electronic Effects on Room-Temperature, Gas-Phase C–H Bond Activations by Cluster Oxides and Metal Carbides: The Methane Challenge

DOI: 10.1021/jacs.7b10139

Experimental and Theoretical Studies on Iron-Promoted Oxidative Annulation of Arylglyoxal with Alkyne: Unusual Addition and Migration on the Aryl Ring

DOI: 10.1021/jacs.7b05981

Selective ortho C–H Activation of Pyridines Directed by Lewis Acidic Boron of PBP Pincer Iridium Complexes

10.1021/jacs.7b10570

Diastereodivergent Asymmetric Carboamination/Annulation of Cyclopropenes with Aminoalkenes by Chiral Lanthanum Catalysts

10.1021/jacs.7b10786

Mechanism of Nakamura’s Bisphosphine-Iron-Catalyzed Asymmetric C(sp2)–C(sp3) Cross-Coupling Reaction: The Role of Spin in Controlling Arylation Pathways

Cation Radical Accelerated Nucleophilic Aromatic Substitution via Organic Photoredox Catalysis

Cooperative Al–H Bond Activation in DIBAL-H: Catalytic Generation of an Alumenium-Ion-Like Lewis Acid for Hydrodefluorinative Friedel–Crafts Alkylation

Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via β-C(sp3)–H Activation

Rhodium/Copper Cocatalyzed Highly trans-Selective 1,2-Diheteroarylation of Alkynes with Azoles via C–H Addition/Oxidative Cross-Coupling: A Combined Experimental and Theoretical Study

Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis

Chemoselective Intermolecular Cross-Enolate-Type Coupling of Amides

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Coupling N–H Deprotonation, C–H Activation, and Oxidation: Metal-Free C(sp3)–H Aminations with Unprotected Anilinesications)