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Nature Chemistry

Monday, December 30, 2019

Cobalt-Catalyzed Oxidative Annulation of Benzothiophene-[b]-1,1-dioxide through Diastereoselective Double C–H Activation

10.1021/acs.orglett.9b03158

Electrochemically Enabled Double C–H Activation of Amides: Chemoselective Synthesis of Polycyclic Isoquinolinones

10.1021/acs.orglett.9b03682

C–H Functionalization Approach for the Synthesis of Chiral C2-Symmetric 1,5-Cyclooctadiene Ligands

10.1021/acs.orglett.9b03764

Redox-Neutral [4 + 2] Annulation of N-Methoxybenzamides with Alkynes Enabled by an Osmium(II)/HOAc Catalytic System

10.1021/acs.orglett.9b03827

Copper-Mediated Direct Cyanation of Heteroarene and Arene C–H Bonds by the Combination of Ammonium and DMF

10.1021/acs.orglett.9b03861

Visible-Light-Enabled Oxidative Coupling of Alkenes with Dialkylformamides To Access Unsaturated Amides

10.1021/acs.orglett.9b03870

Organophotocatalytic Arene Functionalization: C–C and C–B Bond Formation

10.1021/acs.orglett.9b03877

Organic Photoredox-Catalyzed Decarboxylative Trifluoromethylselenolation of Aliphatic Carboxylic Acids with [Me4N][SeCF3]

10.1021/acs.orglett.9b03941

Electrogenerated Sm(II)-Catalyzed CO2 Activation for Carboxylation of Benzyl Halides

Sunday, September 22, 2019

Harnessing Secondary Coordination Sphere Interactions That Enable the Selective Amidation of Benzylic C–H Bonds

10.1021/jacs.9b07795

Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex

10.1021/jacs.9b08185

Para-Selective, Iridium-Catalyzed C–H Borylations of Sulfated Phenols, Benzyl Alcohols, and Anilines Directed by Ion-Pair Electrostatic Interactions

10.1021/jacs.9b08464

Catalytic Cleavage of C(sp2)–C(sp2) Bonds with Rh-Carbynoids

10.1021/jacs.9b08632

Hemilabile Benzyl Ether Enables γ-C(sp3)–H Carbonylation and Olefination of Alcohols

10.1021/jacs.9b08238

Para-Selective C–H Borylation of Common Arene Building Blocks Enabled by Ion-Pairing with a Bulky Countercation

10.1021/jacs.9b07267

Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides

10.1038/s41596-019-0209-8

Fulfilling four roles

10.1002/anie.201908627

Mechanistic Study on the Decarboxylative sp3 C–N Cross-Coupling between Alkyl Carboxylic Acids and Nitrogen Nucleophiles via Dual Copper and Photoredox Catalysis

10.1021/acs.inorgchem.9b01477

Generation of Heteroatom Stereocenters by Enantioselective C–H Functionalization

10.1021/acscatal.9b03194

3-Acetoxyquinuclidine as Catalyst in Electron Donor–Acceptor Complex-Mediated Reactions Triggered by Visible Light

10.1021/acscatal.9b01039

RhCl3·3H2O-Catalyzed Ligand-Enabled Highly Regioselective Thiolation of Acrylic Acids

10.1021/acscatal.9b02982

Recent Advances in Pyridinium Salts as Radical Reservoirs in Organic Synthesis

10.1021/acscatal.9b03084

Copper-Catalyzed Carbon–Silicon Bond Formation

10.1021/acscatal.9b02762

Bifunctional Copper-Based Photocatalyst for Reductive Pinacol-Type Couplings

10.1021/acscatal.9b01718

Alkene Synthesis by Photocatalytic Chemoenzymatically Compatible Dehydrodecarboxylation of Carboxylic Acids and Biomass

10.1021/acscatal.9b02951

Metallalkenyl, Metallacyclopropene, or Metallallylcarbenoid? Ru-Catalyzed Annulation between Benzoic Acid and Alkyne

10.1021/acscatal.9b02952

Nickel/Cobalt-Catalyzed C(sp3)–C(sp3) Cross-Coupling of Alkyl Halides with Alkyl Tosylates

Conjugated Ynones in Organic Synthesis

10.1021/acs.chemrev.9b00277

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